# Labrador Sea HU97048-007PC 58KYr Sediment Source Data #----------------------------------------------------------------------- # World Data Center for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #----------------------------------------------------------------------- # NOTE: Please cite original reference when using these data, # plus the Online Resource and date accessed. # # # Online Resource: https://www.ncdc.noaa.gov/paleo/study/135 ?? # # Original Source URL: http://www1.ncdc.noaa.gov/pub/data/paleo/contributions_by_author/andrews2012/andrews2012.txt # # Description/Documentation lines begin with # # Data lines have no # # # Archive/proxy: Paleoceanography #-------------------- # Contribution Date # Date: 11-14-2012 #-------------------- # Title # Study Name: Labrador Sea HU97048-007PC 58KYr Sediment Source Data #-------------------- # Investigators # Investigators: Andrews, J.T.; Barber, D.C.; Jennings, A.E.; Eberl, D.D.; Maclean, B.; Kirby, M.E.; Stoner, J.S. #-------------------- # Description_Notes_and_Keywords # Description: # Data set includes quantitative X-ray diffraction results and radiocarbon dates from core HU97048-007PC, and other cores, on the NW slope of the Labrador Sea and the mineralogy of bedrock samples from the SE Baffin Island shelf. # # Relative paleomagnetic intensity (RPI, NRM/IRM) from HU97048-007PC is also reported. # IRM=Isothermal Remanent Magnetization # NRM=Natural Remanent Magnetization # # # Suppl. Table 2 # Minerals present BB1 HU85B HU85T HSO-1 HU85Dolo # Quartz 11.5 9.5 19.4 8.1 15.7 # ordered Microcline feldspar 2.2 2.6 3.8 0.0 2.0 # intermediate Microcline feldspar 6.5 9.4 7.6 7.0 9.6 # Orthoclase feldspar 2.3 0.4 0.1 0.3 0.9 # Anorthoclase feldspar 0.0 8.9 11.1 6.7 18.9 # Albite feldspar (Cleavelandite) 4.0 2.2 3.5 1.3 3.3 # Oligoclase feldspar (Norway) 11.3 10.2 17.5 3.7 12.4 # Labradorite feldspar 1.5 6.6 6.9 1.9 2.7 # Calcite 9.6 0.4 0.0 40.6 0.4 # Dolomite 8.2 0.4 0.7 0.2 3.0 # Fe-Dolomite 27.2 1.1 2.4 12.2 2.8 # Amphibole (ferrotschermakite) 0.8 3.0 4.1 1.5 2.9 # Pyroxene (diopside) 3.2 0.5 0.3 0.5 0.0 # Maghemite 0.0 0.4 0.0 0.2 1.3 # Kaolinite (Dry Branch) 0.0 8.7 2.5 0.0 2.1 # Saponite 0.6 13.0 5.4 2.4 5.3 # Ferruginous smectite 0.2 0.7 0.0 0.8 1.6 # "1M illite (R>1, 70-80%I)" 0.0 7.7 7.0 3.2 5.1 # Biotite (1M) 11.0 10.2 5.2 3.8 7.3 # Fe-Chlorite (Tusc) 0.0 4.4 2.4 5.6 2.4 # # # Minerals present BB2 HU85B HU85T HSO-2 HU85Dolo # Quartz 16.8 8.5 16.4 9.8 17.7 # ordered Microcline feldspar 4.3 2.4 3.9 0.0 3.8 # intermediate Microcline feldspar 3.3 9.9 8.3 7.5 6.9 # Orthoclase feldspar 2.9 0.2 0.0 0.4 1.6 # Anorthoclase feldspar 1.8 9.5 14.7 6.9 12.6 # Albite feldspar (Cleavelandite) 2.5 1.2 4.1 0.0 1.7 # Oligoclase feldspar (Norway) 10.7 11.5 16.5 3.2 14.6 # Labradorite feldspar 1.5 6.5 6.7 2.1 6.8 # Calcite 9.8 0.2 0.1 41.3 0.7 # Dolomite 11.8 0.0 0.0 0.0 3.8 # Fe-Dolomite 21.7 0.8 2.2 12.5 3.0 # Amphibole (ferrotschermakite) 1.6 2.7 3.3 1.3 3.3 # Pyroxene (diopside) 0.8 0.0 0.0 0.9 0.0 # Maghemite 0.0 0.3 0.0 0.0 0.5 # Kaolinite (Dry Branch) 0.0 9.2 2.6 0.0 1.7 # Saponite 2.7 13.5 4.4 2.0 7.2 # Ferruginous smectite 0.4 0.6 0.0 0.9 0.2 # "1M illite (R>1, 70-80%I)" 2.1 7.4 6.6 2.3 6.2 # Biotite (1M) 4.4 10.9 6.8 3.7 4.3 # Fe-Chlorite (Tusc) 0.8 4.7 3.3 5.0 3.4 # # # Minerals present BB3 CSB-3 CST-3 HSO-3 CSD3 # Quartz 14.9 10.1 19.7 9.0 20.3 # ordered Microcline feldspar 2.9 2.7 3.6 0.0 0.5 # intermediate Microcline feldspar 3.4 9.6 7.6 6.7 11.0 # Orthoclase feldspar 2.4 0.0 0.0 0.4 0.0 # Anorthoclase feldspar 1.1 10.0 13.7 7.2 14.9 # Albite feldspar (Cleavelandite) 2.7 1.0 2.8 0.5 3.3 # Oligoclase feldspar (Norway) 8.9 12.1 16.4 3.5 13.9 # Labradorite feldspar 1.4 5.8 7.0 3.3 4.4 # Calcite 13.7 0.2 0.1 40.7 1.2 # Dolomite 14.6 0.1 0.3 0.0 5.0 # Fe-Dolomite 23.6 0.8 1.7 13.9 2.9 # Amphibole (ferrotschermakite) 1.2 2.9 3.9 1.0 4.1 # Pyroxene (diopside) 0.4 0.0 1.1 0.7 0.0 # Maghemite 0.0 0.0 0.0 0.1 0.5 # Kaolinite (Dry Branch) 0.0 10.2 1.9 0.0 1.9 # Saponite 2.0 11.9 4.8 2.7 2.8 # Ferruginous smectite 0.3 0.4 0.1 1.0 0.9 # "1M illite (R>1, 70-80%I)" 1.9 6.8 5.9 2.4 2.8 # Biotite (1M) 4.0 10.6 6.4 3.0 5.7 # Fe-Chlorite (Tusc) 0.6 4.8 3.1 4.1 3.6 # # # Minerals present BB4 CSB-4 CST-4 HSO-4 CSD4 # Quartz 12.7 10.0 14.0 9.2 20.2 # ordered Microcline feldspar 1.0 2.5 2.5 0.0 2.0 # intermediate Microcline feldspar 5.9 9.9 8.8 6.6 9.8 # Orthoclase feldspar 0.2 1.0 0.0 0.0 0.7 # Anorthoclase feldspar 7.4 11.6 14.0 7.2 14.5 # Albite feldspar (Cleavelandite) 3.1 1.5 3.9 0.1 2.1 # Oligoclase feldspar (Norway) 4.6 9.8 16.0 4.0 14.2 # Labradorite feldspar 1.0 6.8 5.8 3.5 5.2 # Calcite 11.0 0.2 2.2 41.9 1.2 # Dolomite 10.8 0.0 2.1 0.0 5.8 # Fe-Dolomite 21.7 1.3 0.1 11.5 3.0 # Amphibole (ferrotschermakite) 1.5 2.8 3.0 1.0 3.2 # Pyroxene (diopside) 0.8 0.2 1.1 0.6 0.1 # Maghemite 0.6 0.3 0.5 0.7 0.2 # Kaolinite (Dry Branch) 0.0 7.0 2.8 0.0 1.6 # Saponite 6.2 12.0 5.9 3.6 2.3 # Ferruginous smectite 0.3 0.1 0.1 0.9 1.0 # "1M illite (R>1, 70-80%I)" 5.1 7.4 6.0 2.6 4.8 # Biotite (1M) 3.7 10.9 8.9 2.9 5.2 # Fe-Chlorite (Tusc) 2.4 4.7 2.5 3.8 2.9 # # # Minerals present BB5 CSB-5 CST-5 HSO-5 CSD5 # Quartz 16.1 8.9 18.4 9.3 17.3 # ordered Microcline feldspar 2.3 2.5 3.1 0.0 3.3 # intermediate Microcline feldspar 5.6 9.3 8.4 6.5 9.8 # Orthoclase feldspar 0.5 0.0 0.0 0.2 0.0 # Anorthoclase feldspar 6.5 10.6 8.9 8.5 10.4 # Albite feldspar (Cleavelandite) 2.8 1.0 3.4 0.2 2.2 # Oligoclase feldspar (Norway) 5.5 10.3 19.2 3.0 17.5 # Labradorite feldspar 1.2 4.4 7.4 1.5 7.2 # Calcite 9.1 1.1 0.0 43.6 0.7 # Dolomite 11.8 0.0 0.0 0.0 0.8 # Fe-Dolomite 23.7 1.3 2.6 12.0 5.4 # Amphibole (ferrotschermakite) 1.0 2.6 4.2 0.4 3.4 # Pyroxene (diopside) 0.6 0.0 0.8 0.7 0.6 # Maghemite 0.0 0.0 0.0 0.5 0.4 # Kaolinite (Dry Branch) 0.0 13.2 2.2 0.0 2.2 # Saponite 4.4 10.2 4.6 4.6 1.4 # Ferruginous smectite 0.1 0.0 0.0 1.1 1.6 # "1M illite (R>1, 70-80%I)" 3.7 8.8 5.6 2.7 6.1 # Biotite (1M) 3.3 10.5 8.5 2.5 6.4 # Fe-Chlorite (Tusc) 1.9 5.5 2.7 2.9 3.4 # # # # JQS 2535 supporting Table S1. # # Latitudes and longitudes of core sites. # # Id Fig. 1 Core Id Long Lat # #9 AKPATOK IS -68 60.3 # #3 HU82034-067 -68.33 61.36 # #1 HU82034-066 -68.41 61.37 # HU75009-IV-055 -58.645 61.505 # 56 HU75009-IV-056 -58.558 61.448 # 30 HU90023-030 -63.826 61.788 # #2 HU85027-085 -70.04 62.27 # #4 HU85027-80 -72.45 62.27 # 9 HU87033-009 -59.447 62.5165 # #5 HU75009-004 -63.26 62.58 # 7 HU97048-007 -60.573 62.673 # #6 HU77027-028 -63.2 63.11 # #8 HU75009-005 -63.54 63.16 # #7 HU77027-026A -63.38 63.39 # 6 HU2008029-006 -58.134 64.393 # 41 HU82034-41 -62.44 64.425 # A HU82034-38 -64.581 64.8165 # 25 HU85027-025 -64.966 64.933 # B HU85027-48 -65.216 65.006 # 29 HU85027-029 -64.991 65.042 # C HU85027-31 -65.508 65.389 # SU5 HU82-SU5 -61.71 66.556 # BC06 JCR175BC06 -63.06 69.933 # 31P DA04-31P -54.366 62.563 # # # # # Bedrock samples HU85-025PC HU820038 HU85-048 HU82034-066 HU85027-085 HU75009-004 AKPATOK IS HU77027-028 HU75009-005 HU77027-026A # JQS 2535 supporting Table S3. # # Composition of bedrock samples. # # "Sample name (Fig, 1; Table 1)" 25 A B carb#1 carb#2 carb#5 carb#9 carb#6 carb#8 carb#7 # Full pattern degree of fit: 0.129 0.104 0.102 0.161 0.213 0.316 0.196 0.191 0.213 0.256 # Mineral Weight % Weight % Weight % Weight % Weight % Weight % Weight % Weight % Weight % Weight % # # NON-CLAYS # Quartz 36.7 22.0 15.1 2.2 0.1 1.3 1.7 3.2 1.4 0.8 # ordered Microcline feldspar 1.8 0.0 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 # intermediate Microcline feldspar 6.1 6.7 6.0 1.7 1.4 3.5 2.0 0.4 0.0 0.0 # Orthoclase feldspar 0.1 2.2 1.1 0.2 0.0 9.0 0.0 0.0 0.0 0.1 # Anorthoclase feldspar 8.7 0.3 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 # Albite feldspar 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.3 # Oligoclase feldspar 0.0 0.0 0.0 0.1 0.1 0.0 0.0 0.9 0.1 0.0 # Labradorite feldspar 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.4 0.0 # Bytownite feldspar 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.6 # Anorthite feldspar 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.3 0.2 0.8 # Calcite 0.8 0.9 0.0 77.1 72.5 5.9 73.0 74.9 65.2 74.9 # Dolomite 2.4 0.3 0.1 0.0 4.6 16.8 0.0 0.0 1.7 0.2 # Fe-Dolomite 4.5 0.0 0.0 1.9 7.7 39.4 1.2 1.7 13.0 0.3 # Siderite 1.3 2.6 2.8 0.0 0.1 0.4 0.0 0.0 0.0 0.0 # Amphibole 1.0 0.1 0.0 0.2 0.3 2.5 0.9 0.5 0.8 1.5 # Pyroxene 0.0 0.2 0.0 2.1 2.0 4.1 5.0 3.7 4.9 5.7 # Pyrite 0.1 0.2 0.2 0.1 0.1 0.3 0.1 0.1 0.2 0.3 # Magnetite 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 # Hematite 0.0 0.0 0.0 0.0 0.0 0.5 0.0 0.0 0.0 0.0 # Maghemite 0.0 0.0 0.4 0.7 0.5 0.5 1.0 1.3 0.5 0.7 # amorphous silica 5.0 6.3 8.0 7.1 6.5 6.6 7.8 7.1 6.8 7.9 # Chert (8.4 nm) 6.3 7.9 10.6 0.5 0.0 0.5 0.5 1.3 0.8 0.7 # Total non-clays 75.2 49.6 44.4 93.9 95.9 91.8 93.5 95.7 96.0 95.0 # # CLAYS # Kaolinite 8.3 17.2 16.5 0.0 0.0 0.0 0.0 0.0 0.0 0.0 # Saponite 3.6 3.9 3.2 2.6 1.6 1.9 4.8 4.1 3.9 4.5 # Ferruginous smectite 1.3 2.3 3.6 1.5 1.1 0.0 1.0 0.0 0.0 0.1 # 1Md illite 0.1 3.9 6.1 0.0 0.0 0.4 0.0 0.0 0.0 0.0 # 1M Illite (R>2; 88%I) 0.4 2.5 3.0 0.0 0.0 0.5 0.0 0.0 0.0 0.0 # "1M illite (R>1, 70-80%I)" 4.4 6.6 4.9 0.0 0.0 0.9 0.0 0.0 0.0 0.2 # Biotite (1M) 3.9 3.8 3.4 1.5 1.3 1.8 0.6 0.2 0.0 0.0 # Fe-Chlorite 2.5 4.9 7.2 0.4 0.1 1.6 0.1 0.0 0.0 0.1 # Muscovite (2M1) 0.1 3.5 5.1 0.0 0.0 1.1 0.0 0.0 0.0 0.0 # "Illite (1M, PD3B)" 0.1 1.8 2.5 0.0 0.0 0.0 0.0 0.0 0.0 0.0 # Total clays 24.8 50.4 55.6 6.1 4.1 8.2 6.5 4.3 4.0 5.0 # # # # # # # JQS 2535 supporting Table S4. # # Mineralogy of core HU—041. # # HU82034-41PC # Depth cm 159 210 262 309 # Full pattern degree of fit: 0.099 0.090 0.086 0.119 # Mineral Weight % Weight % Weight % Weight % # # NON-CLAYS # Quartz 24.4 15.9 13.6 34.8 # ordered Microcline feldspar 3.7 4.1 3.9 5.4 # intermediate Microcline feldspar 3.7 4.5 4.2 4.4 # Orthoclase feldspar 2.3 1.6 1.9 3.8 # Anorthoclase feldspar 6.6 6.7 6.6 6.4 # Albite feldspar 2.1 1.8 1.3 1.6 # Oligoclase feldspar 10.5 7.7 7.6 8.6 # Labradorite feldspar 6.1 4.7 4.7 6.7 # Bytownite feldspar 0.1 0.6 0.5 0.0 # Anorthite feldspar 0.0 0.0 0.0 0.0 # Calcite 1.5 0.2 0.4 1.3 # Dolomite 0.7 0.1 0.6 0.3 # Fe-Dolomite 2.6 1.5 1.3 1.0 # Siderite 0.0 0.1 0.4 0.0 # Halite 0.0 0.2 0.6 0.0 # Amphibole 3.0 1.6 1.9 1.2 # Pyroxene 1.6 0.7 0.2 1.3 # Pyrite 0.0 0.1 0.2 0.0 # Magnetite 0.0 0.0 0.0 0.0 # Hematite 0.0 0.0 0.0 0.0 # Maghemite 0.0 0.0 0.0 0.0 # Diatoms 3.9 4.5 4.3 2.4 # Chert (8.4 nm) 8.6 9.4 8.7 8.3 # # Total non-clays 81.5 66.1 62.8 87.6 # # CLAYS # Kaolinite 1.4 11.2 12.1 2.1 # Saponite 2.7 4.6 5.1 0.4 # Ferruginous smectite 0.3 0.6 1.0 0.0 # 1Md illite 0.0 0.8 1.5 0.0 # 1M Illite (R>2; 88%I) 1.6 3.1 3.5 1.4 # "1M illite (R>1, 70-80%I)" 3.0 3.8 3.8 2.3 # Biotite (1M) 1.3 1.9 2.0 1.6 # Fe-Chlorite 6.7 7.2 6.8 4.6 # Muscovite (2M1) 1.6 0.7 1.1 0.0 # "Illite (1M, PD3B)" 0.0 0.0 0.3 0.0 # # Total clays 18.5 33.9 37.2 12.4 # # TOTAL 100.0 100.0 100.0 100.0 # # # # # # JQS 2535 supporting Table S5. # # Mineralogy of the four source areas. # # End Members SedUnMIx # Minerals present Hudson St Baffin Bay CS-base CS--uoper # Quartz 8.1 11.5 9.5 19.4 # ordered Microcline feldspar 0.0 2.2 2.6 3.8 # intermediate Microcline feldspar 7.0 6.5 9.4 7.6 # Orthoclase feldspar 0.3 2.3 0.4 0.1 # Anorthoclase feldspar 6.7 0.0 8.9 11.1 # Albite feldspar 1.3 4.0 2.2 3.5 # Oligoclase feldspar 3.7 11.3 10.2 17.5 # Labradorite feldspar 1.9 1.5 6.6 6.9 # Calcite 40.6 9.6 0.4 0.0 # Dolomite 0.2 8.2 0.4 0.7 # Fe-Dolomite 12.2 27.2 1.1 2.4 # Amphibole 1.5 0.8 3.0 4.1 # Pyroxene 0.5 3.2 0.5 0.3 # Maghemite 0.2 0.0 0.4 0.0 # Kaolinite 0.0 0.0 8.7 2.5 # Saponite 2.4 0.6 13.0 5.4 # Ferruginous smectite 0.8 0.2 0.7 0.0 # "1M illite (R>1, 70-80%I)" 3.2 0.0 7.7 7.0 # Biotite (1M) 3.8 11.0 10.2 5.2 # Fe-Chlorite (Tusc) 5.6 0.0 4.4 2.4 # # # # # # #-------------------- # Publication/Citation # Authors: J.T. Andrews, D.C. Barber, A.E. Jennings, D.D. Eberl, B. Maclean, M.E. Kirby, J.S. Stoner # Published Date or YEAR: 05-17-2012 # Published Title: Varying sediment sources (Hudson Strait, Cumberland Sound, Baffin Bay) to the NW Labrador Sea slope between and during Heinrich events 0 to 4 # Journal Name: Journal of Quaternary Science # Volume: 27 # Issue: 5 # Pages: 475-484 # DOI: 10.1002/jqs.2535 # Abstract: Core HU97048-007PC was recovered from the continental Labrador Sea slope at a water depth of 945 m, 250 km seaward from the mouth of Cumberland Sound, and 400 km north of Hudson Strait. Cumberland Sound is a structural trough partly floored by Cretaceous mudstones and Paleozoic carbonates. The record extends from ~10 to 58 ka. On-board logging revealed a complex series of lithofacies, including buff-colored detrital carbonate-rich sediments [Heinrich (H)-events] frequently bracketed by black facies. We investigate the provenance of these facies using quantitative X-ray diffraction on drill-core samples from Paleozoic and Cretaceous bedrock from the SE Baffin Island Shelf, and on the < 2-mm sediment fraction in a transect of five cores from Cumberland Sound to the NW Labrador Sea. A sediment unmixing program was used to discriminate between sediment sources, which included dolomite-rich sediments from Baffin Bay, calcite-rich sediments from Hudson Strait and discrete sources from Cumberland Sound. Results indicated that the bulk of the sediment was derived from Cumberland Sound, but Baffin Bay contributed to sediments coeval with H-0 (Younger Dryas), whereas Hudson Strait was the source during H-events 1-4. Contributions from the Cretaceous outcrops within Cumberland Sound bracket H-events, thus both leading and lagging Hudson Strait-sourced H-events. # #--------------------- # Funding Agency # Funding Agency Name: US National Science Foundation # Grant: OPP-9906812, ATM-0502515, OPP-0713755 #-------------------- # Site Information # Site Name: HU97048-007PC # Location: Ocean>Atlantic Ocean>North Atlantic Ocean # Country: # Northernmost Latitude: 62.673 # Southernmost Latitude: 62.673 # Easternmost Longitude: -60.573 # Westernmost Longitude: -60.573 # Elevation: m #------------------ # Data Collection # Core Name: HU97048-007PC2012XRD # First Year: 58000 # Last Year: 0 # Time Unit: Calendar Years before present # Core Length: 7.65 m # Notes: #------------------ # Chronology # # JQS 2535 supporting Table S2. # # AMS dates. # # Depth cm Lab. number 14C age ± error cal mid yr BP ±2 sigma # HU97048-007PC # 207-211 AA-31260 14660 120 17292.5 381.5 # 279-283 AA-27758 17624 160 20516 587 # 351-356 AA-31269 21370 270 25050 743 # 572-576 AA-35170 25360 240 29822 491 # 680-684 AA-35171 32000 600 36020.5 1220.5 # 715-718 AA-27759 35290 880 39642 1974 # # Heinrich events HU97048-007PC RPI(Fig. 4) # 207-211 Base H-1 17500 # 351-356 Base H-2 23050 # 680-684 Base H-4 37120 # # # HU85027-029PC # 102 AA-1915 2890 115 2560 263 # 790 AA-1916 9340 84 10101 248 # 996-998 AA-3586 10010 110 10896 274 # # Poly fit age 14C cal and rpi # #------------------ # Variables # # End Description/Documentation (lines begin with #) # Data lines follow (have no #) # Data line variables format: Variables list, one per line, shortname-tab-longname-tab-longname components (9 components: material, error, units, anomaly, period, archive, detail, method, C or N for Character or Numeric data) # Data line format: tab-delimited text, variable short name as header # Missing values -999 # HU97048-007PC XRD wt% data ## depth_cm Depth (cm), , , cm, , , , ## DOF Full pattern degree of fit, , , , , , , ,N ## quartz% Quartz weight percent, , , , , , , ,N ## feldsparOM% ordered Microcline feldspar, , , , , , , ,N ## feldsparIM% intermediate Microcline feldspar, , , , , , , ,N ## feldsparK% kspar, , , , , , , ,N ## feldsparKnoC% kspar w/o carb, , , , , , , ,N ## feldsparOr% Orthoclase feldspar, , , , , , , ,N ## feldsparAnc% Anorthoclase feldspar, , , , , , , ,N ## feldsparAl% Albite feldspar (Cleavelandite), , , , , , , ,N ## feldsparOl% Oligoclase feldspar (Norway), , , , , , , ,N ## feldsparPl% Plagioclase, , , , , , , ,N ## feldsparPlnoC% Plagioclase w/o carb, , , , , , , ,N ## feldsparLa% Labradorite feldspar, , , , , , , ,N ## feldsparBy% Bytownite feldspar, , , , , , , ,N ## feldsparAnt% Anorthite feldspar, , , , , , , ,N ## calcite% Calcite, , , , , , , ,N ## carb% Total carbonate, , , , , , , ,N ## dolo Total dolomite, , , , , , , ,N ## calcite-dolo Calcite:dolomite ratio, , , , , , , ,N ## dolo% Dolomite, , , , , , , ,N ## doloFe% Fe-Dolomite, , , , , , , ,N ## siderite% Siderite, , , , , , , ,N ## halite% Halite, , , , , , , ,N ## amphibole% Amphibole (ferrotschermakite), , , , , , , ,N ## pyroxene% Pyroxene (diopside), , , , , , , ,N ## pyrite% Pyrite, , , , , , , ,N ## magnetite% Magnetite, , , , , , , ,N ## hematite% Hematite, , , , , , , ,N ## maghemite% Maghemite, , , , , , , ,N ## numdia Number of diatoms counted, , , , , , , ,N ## chert% Chert (8.4 nm), , , , , , , ,N ## non-clay% Total non-clays, , , , , , , ,N ## kaolinite% Kaolinite (Dry Branch), , , , , , , ,N ## saponite% Saponite, , , , , , , ,N ## smectiteFe% Ferruginous smectite, , , , , , , ,N ## illite1Md% 1Md illite (+ dioct mica & smectite), , , , , , , ,N ## kaolinitenoC% kao w/o carb, , , , , , , ,N ## smectitenoC% smectite w/o carb, , , , , , , ,N ## smectite% smectites, , , , , , , ,N ## illite1M88% 1M Illite (R>2; 88%I), , , , , , , ,N ## illite1M70% 1M illite (R>1, 70-80%I), , , , , , , ,N ## biotite% Biotite (1M), , , , , , , ,N ## chloriteFe% Fe-Chlorite (Tusc), , , , , , , ,N ## muscovite% Muscovite (2M1), , , , , , , ,N ## illite1MPD3B% Illite (1M, PD3B), , , , , , , ,N ## clay% Total clays, , , , , , , ,N ## TOTAL TOTAL, , , , , , , ,N #------------------------ # Data: # Missing Value: NA depth_cm DOF quartz% feldsparOM% feldsparIM% feldsparK% feldsparKnoC% feldsparOr% feldsparAnc% feldsparAl% feldsparOl% feldsparPl% feldsparPlnoC% feldsparLa% feldsparBy% feldsparAnt% calcite% carb% dolo calcite-dolo dolo% doloFe% siderite% halite% amphibole% pyroxene% pyrite% magnetite% hematite% maghemite% numdia chert% non-clay% kaolinite% saponite% smectiteFe% illite1Md% kaolinitenoC% smectitenoC% smectite% illite1M88% illite1M70% biotite% chloriteFe% muscovite% illite1MPD3B% clay% TOTAL 2 0.1006 9.6 2.6 4.9 7.5 7.5 0.0 14.5 4.9 9.3 5.8 6.3 4.3 0.3 1.2 0.2 8.1 7.9 1.0 0.3 7.6 0.0 1.1 3.4 0.7 0.1 0.0 0.0 2.1 2.5 8.7 78.6 0.4 9.3 0.8 0.0 0.4 11.0 10.1 0.1 3.8 5.0 1.7 0.2 0.0 21.4 100.0 11 0.0948 14.2 1.7 6.2 7.9 8.6 0.0 10.3 1.9 5.8 2.6 3.7 2.4 0.2 0.0 8.0 30.3 22.3 1.4 8.9 13.4 0.3 0.5 2.2 0.2 0.1 0.1 0.0 0.0 4.4 3.3 83.9 0.0 2.7 1.5 0.0 0.0 6.0 4.2 0.0 3.9 5.0 3.0 0.0 0.0 16.1 100.0 20 0.1217 10.6 0.7 6.3 7.0 7.5 0.0 11.1 4.6 4.7 3.4 4.5 3.1 0.0 0.3 6.2 24.5 18.3 1.3 9.0 9.3 0.6 0.4 3.0 1.3 0.2 0.0 0.2 1.4 4.0 3.2 80.3 0.0 6.6 0.0 0.0 0.0 8.7 6.6 0.0 4.7 4.0 4.5 0.0 0.0 19.8 100.0 29 0.1080 9.7 0.0 6.2 6.2 6.8 0.0 9.4 4.0 4.2 4.3 6.0 3.0 1.3 0.0 8.2 28.9 20.7 1.4 8.4 12.3 0.7 0.5 2.3 0.9 0.2 0.0 0.1 1.2 4.4 4.8 81.7 0.0 6.7 0.2 0.0 0.0 9.7 6.9 0.0 4.5 3.7 3.2 0.0 0.0 18.3 100.0 38 0.0962 11.3 0.0 6.3 6.3 7.1 0.0 10.1 2.2 5.2 1.8 2.8 1.8 0.0 0.0 11.0 35.5 24.5 1.4 10.0 14.5 0.5 0.3 2.1 0.1 0.2 0.0 0.2 0.2 4.6 3.3 83.9 0.1 2.8 1.9 0.0 0.2 7.3 4.7 0.1 3.9 4.7 2.6 0.0 0.0 16.1 100.0 47 0.1122 13.0 0.4 6.1 6.5 7.2 0.5 10.5 3.0 2.9 4.1 6.3 3.6 0.0 0.5 10.0 34.4 24.4 1.4 12.4 12.0 0.3 0.3 1.7 0.3 0.2 0.1 0.0 0.7 3.8 2.3 85.0 0.0 4.4 0.0 0.0 0.0 6.7 4.4 0.0 3.2 3.7 3.7 0.1 0.0 15.0 100.0 55 0.1095 14.3 0.4 6.5 6.9 7.6 0.3 10.7 2.8 4.9 1.8 2.6 1.7 0.0 0.1 9.0 31.8 22.8 1.4 9.1 13.7 0.6 0.2 1.7 0.7 0.1 0.1 0.2 0.0 4.5 3.5 85.0 0.0 1.6 1.5 0.0 0.0 4.5 3.1 0.0 3.9 5.0 2.9 0.0 0.0 14.9 100.0 64 0.0967 18.0 1.2 6.5 7.7 7.8 0.1 12.4 2.3 11.7 8.1 8.9 5.7 1.5 0.9 1.4 8.5 7.1 1.2 1.8 5.3 0.4 0.2 3.5 0.8 0.3 0.2 0.3 0.2 4.5 3.5 82.6 0.4 3.4 1.9 0.0 0.4 5.8 5.3 0.1 4.3 4.8 2.6 0.0 0.0 17.4 100.0 73 0.1124 9.0 1.9 4.2 6.1 6.1 0.0 13.2 4.5 10.6 8.1 8.4 6.4 0.2 1.5 0.2 3.6 3.4 1.1 0.0 3.4 0.5 0.7 3.9 1.3 0.2 0.2 0.0 4.3 4.8 9.9 80.7 0.7 2.7 3.7 0.0 0.7 6.6 6.4 0.0 3.4 5.2 3.6 0.0 0.0 19.3 100.0 82 0.1258 14.9 0.4 8.5 8.9 8.9 0.0 12.9 3.5 13.2 7.7 8.0 6.8 0.0 0.9 0.1 3.2 3.1 1.0 1.5 1.6 1.0 0.8 4.2 0.4 0.3 0.2 0.1 2.8 3.3 2.3 79.8 1.0 5.5 1.9 0.0 1.0 7.6 7.4 0.0 3.4 5.4 2.9 0.0 0.0 20.2 100.0 91 0.0960 12.7 0.7 6.0 6.7 6.7 0.0 11.6 2.7 11.9 9.1 9.4 8.3 0.8 0.0 0.3 3.7 3.4 1.1 0.2 3.2 0.5 0.7 5.1 0.9 0.2 0.1 0.2 1.3 5.0 4.2 76.7 1.8 5.0 2.5 0.0 1.9 7.8 7.5 0.0 4.4 6.4 3.1 0.0 0.0 23.3 100.0 100 0.1154 13.5 1.4 5.7 7.1 7.1 0.0 12.8 2.7 11.9 7.8 8.1 7.7 0.0 0.1 0.3 3.5 3.2 1.1 0.5 2.7 0.5 1.1 5.2 1.0 0.1 0.2 0.2 1.5 4.6 2.9 76.7 1.5 5.2 2.6 0.0 1.6 8.1 7.8 0.0 5.0 6.0 3.0 0.0 0.0 23.3 100.0 109 0.1209 16.1 0.0 6.6 6.6 6.6 0.0 17.5 2.3 12.3 6.7 7.0 5.0 1.7 0.0 0.2 3.9 3.7 1.1 1.7 2.0 0.6 0.4 5.3 0.0 0.2 0.3 0.2 0.9 4.0 1.7 79.0 1.2 4.9 1.9 0.0 1.2 7.1 6.8 0.0 5.9 5.4 1.7 0.0 0.0 21.0 100.0 118 0.1017 14.4 1.6 5.7 7.3 7.3 0.0 13.2 2.3 12.6 7.0 7.3 7.0 0.0 0.0 0.2 4.1 3.9 1.1 1.2 2.7 0.6 0.5 4.9 1.1 0.2 0.0 0.0 1.4 4.5 3.1 77.4 2.0 4.8 2.6 0.0 2.1 7.7 7.4 0.0 4.7 5.8 2.8 0.0 0.0 22.6 100.0 127 0.0856 13.7 1.5 5.9 7.4 7.5 0.0 11.3 2.5 12.0 8.4 8.9 7.0 1.4 0.0 0.8 5.6 4.8 1.2 0.0 4.8 0.2 0.6 4.5 0.9 0.3 0.2 0.0 1.2 4.3 4.4 77.6 1.6 6.6 2.7 0.0 1.7 9.9 9.3 0.0 4.1 5.1 2.2 0.0 0.0 22.4 100.0 136 0.0906 13.7 1.2 6.0 7.2 7.3 0.0 12.9 1.8 11.6 6.1 6.6 5.9 0.2 0.0 1.4 7.0 5.6 1.3 1.9 3.7 0.6 0.6 4.4 0.7 0.2 0.0 0.1 1.2 4.7 3.5 76.2 2.2 5.3 2.6 0.0 2.4 8.5 7.9 0.0 5.1 5.9 2.7 0.0 0.1 23.8 100.0 146 0.0884 18.1 1.5 5.9 7.4 7.6 0.0 11.8 2.1 11.0 6.2 7.0 4.7 1.5 0.0 2.3 10.9 8.6 1.3 2.7 5.9 0.2 0.4 3.9 1.1 0.3 0.0 0.0 0.9 4.8 4.9 83.8 0.8 2.1 1.8 0.0 0.9 4.4 3.9 0.0 4.1 5.3 2.1 0.0 0.0 16.2 100.0 145 0.1378 19.3 2.1 5.5 7.6 7.7 0.4 17.1 2.2 12.3 6.0 6.3 5.9 0.0 0.1 0.9 4.0 3.1 1.3 2.7 0.4 0.7 0.2 4.9 0.3 0.2 0.0 0.1 2.3 2.4 3.0 82.9 0.2 7.8 0.0 0.0 0.2 8.1 7.8 0.0 3.2 3.7 2.1 0.0 0.0 17.2 100.0 164 0.1094 26.8 5.0 4.4 9.4 9.6 0.0 7.3 2.2 13.0 8.4 9.2 7.3 1.1 0.0 2.0 8.2 6.2 1.3 1.3 4.9 0.0 0.3 2.1 2.1 0.2 0.0 0.0 0.0 3.6 5.4 89.0 0.7 1.0 1.9 0.0 0.8 3.2 2.9 1.7 1.4 3.4 0.8 0.0 0.1 11.0 100.0 173 0.1084 28.4 4.0 5.0 9.0 9.1 0.6 7.1 1.5 11.6 6.7 7.0 6.0 0.7 0.0 0.9 4.4 3.5 1.3 0.0 3.5 0.0 0.4 1.8 1.1 0.0 0.0 0.0 0.0 3.5 6.6 82.7 2.5 2.0 2.3 0.0 2.6 4.5 4.3 3.0 2.9 3.2 1.5 0.0 0.0 17.3 100.0 182 0.0931 13.1 1.5 5.7 7.2 7.4 0.0 15.5 3.7 9.9 5.3 5.6 3.9 1.1 0.3 2.8 5.8 3.0 1.9 1.1 1.9 0.0 0.8 4.1 0.0 0.2 0.0 0.0 2.4 3.1 4.9 76.0 1.3 9.6 0.4 0.0 1.4 10.6 10.0 0.7 4.8 4.5 2.7 0.0 0.1 23.9 100.0 191 0.0913 8.7 0.5 6.4 6.9 7.4 0.0 10.8 3.1 7.6 4.8 5.4 2.7 1.5 0.6 6.6 10.7 4.1 2.6 0.3 3.8 0.1 1.2 2.7 0.1 0.3 0.0 0.1 1.6 6.4 8.7 73.6 1.7 8.1 2.9 0.0 1.9 12.3 11.0 0.4 5.5 4.6 3.2 0.0 0.0 26.4 100.0 200 0.0858 13.9 0.1 5.4 5.5 6.7 0.0 12.8 1.9 5.0 2.1 2.9 1.3 0.1 0.7 18.2 26.5 8.3 3.2 1.5 6.8 0.4 0.7 1.3 0.0 0.3 0.0 0.0 1.1 3.6 3.9 78.8 1.7 5.5 0.6 0.0 2.3 8.3 6.1 0.6 5.3 3.7 2.7 0.8 0.4 21.2 100.0 202 0.0910 14.5 0.5 5.3 5.8 7.9 0.0 8.9 2.0 4.8 1.5 2.4 1.1 0.2 0.2 26.5 37.2 10.7 3.5 0.4 10.3 0.2 0.5 1.4 0.0 0.2 0.0 0.2 0.1 3.6 2.7 83.5 0.8 3.5 1.5 0.4 1.3 8.6 5.4 0.7 3.9 2.6 2.8 0.1 0.0 16.5 100.0 209 0.0901 11.8 0.0 6.1 6.1 7.4 0.0 9.4 2.1 5.7 1.8 2.4 1.5 0.3 0.0 17.3 25.5 8.2 3.1 1.3 6.9 0.4 1.2 1.4 0.0 0.3 0.0 0.0 0.9 6.4 7.2 80.1 1.1 5.2 2.5 0.0 1.5 10.3 7.7 0.1 3.9 4.2 2.9 0.0 0.0 19.9 100.0 218 0.0812 10.9 1.7 5.0 6.7 6.9 0.0 8.6 2.8 8.6 4.2 4.5 3.3 0.7 0.2 3.2 7.1 3.9 1.8 1.5 2.4 0.5 1.1 2.8 0.0 0.5 0.0 0.0 1.5 5.6 5.2 65.8 2.1 9.0 3.4 0.0 2.3 13.3 12.4 1.3 8.2 4.4 5.0 0.9 0.0 34.2 100.0 227 0.1012 12.8 0.9 6.4 7.3 7.5 0.0 12.2 3.3 7.9 2.2 2.4 2.2 0.0 0.0 2.6 6.8 4.2 1.6 0.3 3.9 0.6 0.9 3.3 0.0 0.7 0.0 0.2 0.9 5.2 3.3 67.8 2.5 6.8 3.4 1.3 2.7 12.3 11.5 0.7 7.8 5.2 3.9 0.6 0.0 32.2 100.0 236 0.0864 15.2 2.4 4.8 7.2 7.4 0.0 9.1 3.4 12.4 7.0 7.4 5.6 1.2 0.2 3.1 4.9 1.8 2.7 0.0 1.8 0.3 1.0 3.0 0.7 0.4 0.0 0.0 0.8 5.4 4.5 75.6 1.1 6.8 2.8 0.0 1.2 10.1 9.6 0.0 5.4 4.1 4.2 0.0 0.0 24.4 100.0 245 0.0928 25.2 2.9 5.6 8.5 8.8 0.0 11.7 2.7 11.2 8.1 8.5 6.0 2.1 0.0 2.9 4.5 1.6 2.8 0.0 1.6 0.3 0.3 2.7 0.3 0.2 0.1 0.0 0.1 4.3 3.6 83.9 0.0 2.8 2.2 0.0 0.0 5.2 5.0 0.0 4.6 4.1 2.3 0.0 0.0 16.1 100.0 250 0.0875 18.0 3.6 5.6 9.2 9.3 3.8 10.0 2.5 8.8 4.9 5.1 4.9 0.0 0.0 1.6 3.7 2.1 1.8 0.0 2.1 0.9 0.3 2.2 0.2 0.2 0.0 0.0 0.5 1.3 9.4 75.9 3.3 2.4 3.1 0.0 3.4 5.7 5.5 2.6 3.8 3.4 5.3 0.1 0.0 24.1 100.0 254 0.1089 16.3 1.7 6.1 7.8 8.1 0.1 13.8 3.0 11.4 5.9 6.2 5.9 0.0 0.0 3.3 4.9 1.6 3.1 0.6 1.0 0.6 0.4 3.8 0.5 0.3 0.0 0.1 1.2 5.2 4.4 79.5 0.6 5.8 1.7 0.0 0.6 7.9 7.5 0.0 4.3 4.6 3.6 0.0 0.0 20.5 100.0 263 0.1121 12.4 4.1 2.7 6.8 7.0 1.0 5.0 5.1 12.8 8.3 8.8 8.0 0.3 0.0 3.5 5.4 1.9 2.8 0.0 1.9 0.3 0.8 2.9 0.9 0.6 0.0 0.0 2.0 7.3 7.3 78.9 0.7 5.9 1.9 0.6 0.7 8.9 8.4 1.1 4.0 2.2 4.6 0.0 0.1 21.1 100.0 272 0.1054 18.3 2.9 5.1 8.0 8.5 0.0 12.2 3.3 11.4 6.2 6.7 5.0 0.0 1.2 5.8 7.6 1.8 4.2 0.0 1.8 0.4 0.3 2.9 1.1 0.5 0.0 0.2 0.6 5.5 4.4 82.8 0.3 3.3 1.8 0.0 0.3 5.5 5.1 0.1 4.0 3.9 3.6 0.0 0.0 17.2 100.0 276 0.0905 19.3 2.2 5.9 8.1 8.7 0.0 12.3 3.2 11.6 6.1 6.6 5.7 0.4 0.0 6.7 8.2 1.5 5.5 0.0 1.5 0.3 0.4 3.4 1.1 0.3 0.0 0.1 0.0 4.6 4.4 83.3 0.6 2.8 2.3 0.0 0.7 5.6 5.1 0.0 4.5 4.3 2.4 0.0 0.0 16.7 100.0 281 0.0911 17.9 2.3 6.2 8.5 9.0 0.0 12.0 3.5 10.7 7.7 8.3 5.8 0.8 1.1 5.2 7.0 1.8 3.9 0.0 1.8 0.3 0.5 3.2 1.2 0.4 0.0 0.1 0.4 4.9 5.2 83.5 0.5 3.3 2.0 0.0 0.5 5.7 5.3 0.0 4.1 4.2 2.4 0.0 0.0 16.5 100.0 291 0.0967 12.0 0.5 6.5 7.0 7.3 0.0 11.3 3.3 5.7 3.9 4.5 3.2 0.7 0.0 4.7 12.8 8.1 1.6 3.5 4.6 0.5 0.5 2.3 0.0 0.2 0.0 0.0 0.9 5.6 4.5 70.7 2.2 7.1 2.5 1.3 2.5 12.5 10.9 1.4 4.8 5.1 3.9 0.5 0.5 29.3 100.0 301 0.0979 24.8 4.8 5.0 9.8 9.9 1.2 12.5 1.2 7.9 5.5 5.6 5.5 0.0 0.0 0.7 2.6 1.9 1.4 0.0 1.9 0.6 0.2 1.1 0.0 0.3 0.0 0.0 0.0 4.6 8.0 80.5 3.4 5.1 0.5 0.0 3.5 5.7 5.6 0.0 5.9 2.5 2.0 0.0 0.0 19.5 100.0 309 0.0922 27.9 3.0 5.3 8.3 8.4 3.0 9.5 1.3 9.9 5.0 5.2 5.0 0.0 0.0 1.4 4.2 2.8 1.5 0.6 2.2 0.8 0.3 2.4 0.6 0.1 0.0 0.0 0.5 1.2 7.7 82.8 2.2 1.3 2.4 0.0 2.3 3.9 3.7 1.1 3.2 3.1 3.8 0.0 0.0 17.2 100.0 327 0.0944 10.7 0.9 4.4 5.3 7.5 0.0 9.6 2.8 3.1 0.7 1.2 0.7 0.0 0.0 29.5 41.9 12.4 3.4 1.1 11.3 0.2 0.3 0.7 0.9 0.2 0.0 0.0 1.2 4.7 7.0 89.4 0.2 0.0 3.2 0.0 0.3 5.5 3.2 0.4 0.2 4.1 2.2 0.4 0.0 10.6 100.0 335 0.1204 10.1 0.0 3.8 3.8 5.7 0.0 10.9 2.2 2.7 0.4 0.7 0.4 0.0 0.0 33.6 45.2 11.6 3.9 0.0 11.6 0.6 0.3 1.1 0.4 0.1 0.0 0.1 2.0 5.7 2.5 88.0 0.0 4.8 0.8 0.0 0.0 10.2 5.6 0.0 3.2 1.2 1.6 0.3 0.0 12.0 100.0 353 0.0875 17.3 1.4 8.2 9.6 10.0 0.0 5.6 1.6 12.7 6.0 6.6 5.1 0.9 0.0 3.7 8.8 5.1 1.7 0.7 4.4 0.0 0.9 2.7 0.8 0.1 0.0 0.1 0.0 3.7 5.7 75.3 2.4 4.1 3.6 0.0 2.6 8.4 7.7 3.9 2.5 4.7 2.7 0.8 0.0 24.7 100.0 361 0.1075 18.5 3.7 5.5 9.2 9.5 0.0 5.0 3.6 13.6 9.5 10.3 7.7 1.8 0.0 3.3 8.1 4.8 1.7 0.0 4.8 0.0 0.7 2.4 1.7 0.1 0.0 0.1 0.0 3.3 6.7 82.5 0.8 2.8 3.4 0.0 0.9 6.7 6.2 0.2 4.3 4.1 1.9 0.0 0.0 17.5 100.0 370 0.1045 30.9 4.3 6.6 10.9 11.3 0.0 6.5 1.8 15.5 7.9 8.6 7.3 0.6 0.0 3.7 7.8 4.1 1.9 0.7 3.4 0.0 0.2 2.5 1.2 0.1 0.0 0.2 0.0 2.2 4.7 92.1 0.5 0.1 2.0 0.0 0.5 2.3 2.1 0.9 1.6 2.1 0.6 0.0 0.0 7.9 100.0 379 0.1027 26.7 3.6 4.6 8.2 8.6 1.6 9.9 2.8 12.2 5.9 6.3 5.7 0.2 0.0 4.6 7.0 2.4 2.9 0.8 1.6 0.5 0.3 3.0 1.0 0.2 0.1 0.2 0.8 3.3 5.3 89.0 0.1 1.0 2.5 0.0 0.1 3.8 3.5 0.2 1.7 3.0 1.7 0.3 0.5 11.0 100.0 388 0.1040 20.5 3.1 5.0 8.1 8.4 0.1 12.4 3.2 12.7 6.4 6.8 5.7 0.2 0.5 4.0 5.6 1.6 3.5 0.0 1.6 0.4 0.4 3.6 0.7 0.4 0.0 0.0 0.9 4.7 3.7 84.0 0.0 3.9 1.7 0.0 0.0 5.9 5.6 0.0 3.5 3.8 3.1 0.0 0.0 16.0 100.0 397 0.0974 17.4 4.1 4.9 9.0 9.4 0.0 9.2 4.2 14.5 7.9 8.4 6.7 1.2 0.0 4.4 6.4 2.0 3.2 0.0 2.0 0.0 0.9 3.9 1.5 0.4 0.0 0.1 0.0 2.3 4.6 82.2 1.0 2.4 4.0 0.0 1.1 6.8 6.4 0.0 1.8 5.2 3.3 0.0 0.0 17.8 100.0 406 0.0895 14.4 2.6 5.6 8.2 8.6 0.0 12.4 3.4 10.3 6.8 7.3 5.9 0.7 0.2 5.1 7.1 2.0 3.6 0.0 2.0 0.6 0.7 3.2 0.4 0.5 0.0 0.2 1.0 4.9 5.7 79.9 0.6 5.7 2.1 0.3 0.6 8.7 8.1 0.7 3.1 5.0 2.8 0.0 0.0 20.1 100.0 415 0.0990 12.3 0.9 6.3 7.2 7.6 0.0 14.8 4.1 8.7 5.5 5.9 5.1 0.0 0.4 5.2 6.6 1.4 4.7 0.0 1.4 0.7 0.7 3.8 0.8 0.4 0.0 0.2 1.3 5.8 8.8 81.6 0.4 5.5 1.8 0.0 0.4 7.8 7.3 0.0 3.6 4.4 2.8 0.0 0.0 18.4 100.0 424 0.0980 20.7 4.4 4.8 9.2 9.9 0.0 3.2 2.6 17.1 9.3 10.3 9.0 0.3 0.0 7.2 9.3 2.1 4.4 0.7 1.4 0.0 0.3 3.2 1.7 0.3 0.0 0.0 0.0 2.9 4.3 84.1 0.8 3.9 2.0 0.0 0.9 6.5 5.9 1.0 3.0 3.5 1.6 0.0 0.0 15.9 100.0 428 0.0919 17.0 3.0 5.1 8.1 8.5 0.0 11.3 3.4 12.2 6.8 7.3 6.7 0.1 0.0 4.9 7.1 2.2 3.2 0.4 1.8 0.3 0.4 3.7 1.0 0.4 0.0 0.2 1.2 3.8 5.5 82.5 0.4 3.8 3.0 0.3 0.4 7.6 7.1 0.5 2.8 3.6 2.8 0.0 0.4 17.4 100.0 434 0.0921 14.6 2.1 5.6 7.7 8.0 0.0 12.1 3.1 13.0 4.8 5.1 3.9 0.5 0.4 4.1 6.2 2.1 3.0 0.0 2.1 0.5 0.7 3.6 0.0 0.5 0.0 0.1 1.6 5.9 4.6 79.1 0.6 4.5 2.1 0.0 0.6 7.0 6.6 0.0 5.2 4.9 3.5 0.0 0.0 21.0 100.0 443 0.0948 17.2 2.1 5.6 7.7 8.1 0.0 13.3 3.2 11.1 6.2 6.6 6.1 0.0 0.1 4.4 6.3 1.9 3.3 0.0 1.9 0.6 0.5 3.8 0.8 0.5 0.0 0.0 0.8 5.4 3.6 80.8 0.0 4.9 1.9 0.0 0.0 7.3 6.8 0.0 4.8 4.6 3.0 0.0 0.0 19.2 100.0 447 0.0860 11.9 2.8 5.3 8.1 8.5 0.0 3.3 3.1 9.4 5.9 6.8 5.0 0.0 0.9 4.7 13.0 8.3 1.6 3.0 5.3 0.2 0.8 3.0 0.7 0.2 0.0 0.0 0.0 3.6 4.2 67.5 2.6 8.4 3.2 2.3 3.0 16.0 13.9 2.7 4.6 4.3 3.5 0.2 0.8 32.5 100.0 465 0.1040 12.6 1.6 5.5 7.1 7.5 0.0 15.2 3.8 10.8 4.7 5.0 4.6 0.0 0.1 5.5 6.9 1.4 4.9 0.0 1.4 0.6 0.6 4.2 0.3 0.5 0.0 0.2 2.0 5.6 4.4 79.5 0.3 5.4 1.7 0.0 0.3 7.6 7.1 0.0 4.7 5.0 3.4 0.0 0.0 20.5 100.0 474 0.0905 14.0 2.1 5.4 7.5 8.0 0.0 12.7 3.8 11.6 5.6 6.1 3.9 0.4 1.3 6.8 8.3 1.5 5.5 0.0 1.5 0.3 0.7 4.3 1.3 0.4 0.0 0.2 0.9 4.5 5.3 81.2 0.7 5.0 1.8 0.0 0.8 7.4 6.8 0.2 3.3 4.9 3.0 0.0 0.0 18.9 100.0 483 0.0934 19.9 4.4 4.8 9.2 9.6 0.0 5.0 3.6 16.3 9.5 10.1 9.5 0.0 0.0 3.8 5.5 1.7 3.2 0.1 1.6 0.0 0.7 3.6 1.3 0.2 0.0 0.1 0.0 3.2 4.2 82.4 0.6 4.2 2.1 0.0 0.6 6.7 6.3 1.0 3.4 3.8 2.4 0.0 0.0 17.6 100.0 492 0.1093 25.4 2.8 6.5 9.3 9.6 0.0 15.4 1.8 11.9 6.5 6.8 5.7 0.8 0.0 2.8 4.4 1.6 2.8 1.2 0.4 0.5 0.1 2.7 0.4 0.2 0.2 0.2 0.1 4.3 6.7 90.1 0.0 2.7 0.6 0.0 0.0 3.5 3.3 0.0 3.1 3.0 0.6 0.0 0.0 9.9 100.0 501 0.0885 15.9 3.2 5.7 8.9 9.0 0.0 14.2 2.6 11.8 7.0 7.2 5.8 1.2 0.0 1.1 2.5 1.4 1.8 0.0 1.4 0.3 0.4 3.3 0.4 0.3 0.0 0.1 1.5 5.4 7.1 81.6 0.4 6.4 1.2 0.0 0.4 7.8 7.6 0.0 4.2 4.8 1.6 0.0 0.0 18.4 100.0 510 0.0960 24.7 4.5 3.9 8.4 8.5 1.4 8.3 2.9 13.1 8.2 8.4 8.2 0.0 0.0 0.9 2.5 1.6 1.6 1.1 0.5 0.4 0.2 2.8 1.1 0.2 0.1 0.1 0.6 5.8 7.0 87.8 0.1 3.3 0.9 0.0 0.1 4.3 4.2 0.0 3.3 2.1 2.6 0.0 0.0 12.2 100.0 519 0.0937 21.9 2.8 5.8 8.6 8.6 0.1 13.6 2.0 11.7 7.4 7.6 6.6 0.8 0.0 0.3 2.5 2.2 1.1 0.1 2.1 0.3 0.3 3.1 0.5 0.2 0.0 0.1 0.2 4.1 7.3 83.9 0.8 2.5 1.3 0.0 0.8 3.9 3.8 0.5 5.0 4.1 1.8 0.0 0.0 16.1 100.0 528 0.0902 21.6 2.7 5.7 8.4 8.5 0.0 13.6 1.8 10.1 5.6 5.8 4.5 0.0 1.1 0.8 3.3 2.5 1.3 0.3 2.2 0.6 0.4 1.8 0.4 0.4 0.0 0.2 0.0 5.3 8.4 81.4 2.1 3.4 1.6 0.0 2.2 5.2 5.0 0.0 5.4 3.9 2.2 0.0 0.0 18.6 100.0 536 0.1242 29.5 3.6 3.8 7.4 7.5 4.3 10.2 2.1 8.1 5.0 5.2 5.0 0.0 0.0 1.1 3.7 2.6 1.4 2.1 0.5 0.9 0.1 2.0 0.1 0.2 0.0 0.0 1.1 4.2 3.4 82.3 2.6 5.4 0.8 0.3 2.7 6.7 6.5 0.4 4.5 1.8 1.9 0.0 0.0 17.7 100.0 545 0.0890 31.7 3.7 4.7 8.4 8.5 1.4 9.6 1.2 9.3 5.2 5.4 5.2 0.0 0.0 0.9 3.8 2.9 1.3 0.6 2.3 0.6 0.2 2.5 0.2 0.2 0.0 0.0 0.6 3.3 5.6 83.9 2.4 2.3 2.5 0.0 2.5 5.0 4.8 0.5 2.6 3.2 2.3 0.1 0.3 16.1 100.0 554 0.0897 24.4 2.9 6.4 9.3 9.4 0.0 13.9 1.0 8.0 4.3 4.5 3.9 0.4 0.0 1.0 3.9 2.9 1.3 0.7 2.2 0.7 0.4 1.1 0.0 0.3 0.0 0.1 0.2 5.1 9.9 82.6 2.6 2.7 1.6 0.0 2.7 4.5 4.3 0.1 5.3 3.6 1.4 0.0 0.0 17.4 100.0 563 0.0934 19.1 1.6 6.9 8.5 8.6 0.4 14.2 2.0 8.2 3.1 3.2 2.4 0.7 0.0 1.7 4.6 2.9 1.6 0.7 2.2 0.7 0.4 2.6 0.0 0.2 0.0 0.0 0.2 5.5 6.4 75.9 3.4 5.6 1.5 0.0 3.6 7.4 7.1 0.7 5.6 4.7 2.6 0.0 0.0 24.1 100.0 574 0.0867 14.4 2.8 5.8 8.6 8.7 0.0 12.5 3.8 11.8 8.1 8.4 6.7 1.4 0.0 1.4 3.2 1.8 1.8 0.0 1.8 0.3 0.7 4.4 0.9 0.3 0.0 0.2 1.0 4.1 5.8 79.9 0.7 6.0 1.6 0.0 0.7 7.9 7.6 0.0 3.9 4.9 2.9 0.0 0.0 20.1 100.0 578 0.0968 19.6 2.8 5.9 8.7 8.9 2.7 4.6 1.4 11.7 6.6 7.0 6.6 0.0 0.0 1.7 5.1 3.4 1.5 1.0 2.4 0.4 0.6 2.3 0.4 0.0 0.0 0.0 0.0 3.7 4.7 72.3 4.5 5.6 2.5 0.5 4.7 9.1 8.6 1.9 4.3 4.6 3.1 0.5 0.2 27.7 100.0 583 0.0872 14.3 2.3 6.3 8.6 8.7 0.0 12.4 2.8 12.8 8.2 8.5 7.0 1.2 0.0 1.5 3.3 1.8 1.8 0.0 1.8 0.3 0.6 3.6 0.6 0.3 0.0 0.1 0.4 4.2 4.0 76.3 1.1 6.3 1.9 0.0 1.1 8.5 8.2 0.0 5.3 5.6 3.5 0.0 0.0 23.7 100.0 592 0.0972 9.8 0.0 6.8 6.8 8.2 0.0 12.6 2.6 5.8 3.7 4.8 3.4 0.3 0.0 16.8 23.1 6.3 3.7 1.6 4.7 0.4 0.5 2.3 0.1 0.3 0.0 0.0 1.0 4.6 5.5 79.1 1.3 6.8 1.7 1.0 1.7 12.4 9.5 1.1 2.6 4.1 1.9 0.4 0.1 20.9 100.0 601 0.0929 14.0 3.6 5.3 8.9 9.4 0.0 7.8 2.9 14.5 8.1 8.8 7.2 0.9 0.0 5.7 8.3 2.6 2.2 0.0 2.6 0.0 0.9 4.0 1.1 0.1 0.0 0.0 0.0 0.8 5.4 76.8 1.6 3.3 5.0 0.0 1.7 1.1 1.0 2.6 6.5 3.2 0.0 0.0 0.0 23.2 100.0 610 0.0950 14.7 3.3 4.5 7.8 8.4 0.4 6.7 2.6 11.3 9.9 11.1 8.4 1.5 0.0 7.0 11.1 4.1 1.7 0.5 3.6 0.0 0.2 3.8 0.9 0.5 0.0 0.0 0.0 1.5 4.1 75.5 1.7 3.7 2.9 0.0 1.9 4.2 3.7 1.5 7.9 2.9 0.0 0.0 0.0 24.4 100.0 619 0.1209 21.1 5.0 4.1 9.1 9.3 0.0 7.3 3.3 15.4 10.4 10.9 8.8 1.6 0.0 2.1 4.8 2.6 0.8 0.0 2.6 0.0 0.3 2.8 2.0 0.1 0.0 0.1 0.0 1.6 5.0 83.1 1.2 1.8 2.3 0.0 1.3 2.6 2.5 0.9 6.4 1.9 0.0 0.0 0.0 17.0 100.0 628 0.1316 33.8 4.0 3.4 7.4 7.5 2.5 2.0 1.6 16.5 6.5 6.9 5.8 0.7 0.0 1.8 6.3 4.5 0.4 1.9 2.6 0.0 0.0 1.1 0.9 0.1 0.1 0.0 0.0 3.4 6.3 88.2 0.3 0.0 0.1 0.0 0.3 1.5 1.4 0.0 7.6 2.0 0.4 0.2 0.0 11.8 100.0 637 0.1079 26.4 3.3 5.5 8.8 9.4 0.0 7.0 2.2 17.2 7.6 8.5 6.8 0.8 0.0 6.2 10.2 4.1 1.5 0.1 4.0 0.0 0.0 2.7 1.1 0.1 0.1 0.1 0.0 0.9 3.3 87.8 0.9 1.4 2.6 0.0 1.0 2.7 2.4 0.3 3.8 0.6 0.0 0.0 0.0 12.2 100.0 642 0.1189 20.5 2.3 5.8 8.1 10.2 0.1 5.5 2.2 9.5 4.8 7.1 4.1 0.7 0.0 20.3 32.0 11.7 1.7 0.7 11.0 0.0 0.1 1.3 0.4 0.1 0.1 0.0 0.0 1.4 3.9 90.3 0.6 0.6 2.5 0.0 0.9 1.9 1.3 0.3 3.4 0.9 0.0 0.0 0.0 9.8 100.0 655 0.1113 17.9 1.5 6.1 7.6 10.3 0.0 4.8 1.9 8.0 4.9 7.9 4.5 0.4 0.0 26.3 37.9 11.6 2.3 0.0 11.6 0.0 0.0 1.3 0.3 0.0 0.0 0.0 0.0 1.4 4.0 89.7 0.4 0.6 2.7 0.0 0.6 2.7 1.7 0.5 3.3 1.2 0.0 0.0 0.0 10.2 100.0 664 0.1199 13.0 2.5 4.5 7.0 9.5 2.0 0.8 2.6 9.3 3.2 5.1 3.2 0.0 0.0 26.2 37.4 11.2 2.3 1.7 9.5 0.0 0.1 1.0 0.7 0.0 0.0 0.1 0.0 4.0 5.7 86.5 0.0 0.0 0.7 0.0 0.0 3.5 2.2 0.0 8.1 1.7 0.7 0.0 0.0 13.5 100.0 673 0.1353 11.6 1.8 4.3 6.1 8.6 1.3 1.4 2.8 8.8 2.9 4.9 2.9 0.0 0.0 29.2 41.3 12.1 2.4 0.0 12.1 0.0 0.1 1.3 0.7 0.1 0.0 0.1 0.0 3.8 4.1 86.5 0.3 0.0 1.8 0.0 0.5 4.3 2.5 0.0 6.0 2.3 0.6 0.0 0.0 13.5 100.0 682 0.0983 16.3 3.2 5.8 9.0 9.2 0.0 7.1 1.9 11.5 7.8 8.7 6.7 1.0 0.1 2.7 10.0 7.3 0.4 0.0 7.3 0.0 0.4 2.7 1.9 0.1 0.0 0.1 0.4 1.6 5.3 76.0 1.7 5.5 3.3 1.3 1.9 3.7 3.3 2.0 4.1 2.9 0.0 0.0 0.0 24.0 100.0 691 0.0912 13.8 2.7 6.0 8.7 8.9 0.0 6.1 2.3 10.5 6.1 6.8 5.1 0.7 0.3 2.6 10.0 7.4 0.4 0.0 7.4 0.0 0.3 2.5 0.8 0.2 0.0 0.1 0.0 2.3 5.6 69.5 2.2 5.1 3.4 0.0 2.4 3.9 3.5 4.9 5.4 5.4 0.5 0.0 0.0 30.5 100.0 700 0.0966 13.0 3.2 5.7 8.9 9.2 0.0 7.3 2.9 10.4 5.9 6.7 4.0 1.9 0.0 3.5 11.8 8.4 0.4 0.0 8.4 0.0 0.9 2.2 1.7 0.2 0.0 0.0 0.0 1.4 5.5 72.1 1.7 5.2 5.1 0.0 1.9 3.6 3.2 3.0 4.6 5.1 0.0 0.0 0.0 27.9 100.0 714 0.1314 27.5 2.4 4.4 6.8 8.0 0.7 3.4 0.8 14.0 9.0 11.0 7.4 1.4 0.2 14.8 18.2 3.4 4.3 0.6 2.8 0.0 0.0 1.9 1.7 0.1 0.4 0.0 0.0 2.9 4.1 91.6 0.3 0.3 1.2 0.0 0.4 2.0 1.6 0.2 4.3 0.2 0.2 0.0 0.0 8.4 100.0 717 0.1534 26.8 2.4 5.3 7.7 8.9 0.0 7.2 1.0 11.1 9.6 11.8 8.7 0.9 0.0 13.5 18.7 5.2 2.6 0.0 5.2 0.0 0.2 1.4 1.8 0.1 0.1 0.0 0.0 1.1 5.4 92.3 0.2 0.1 2.7 0.0 0.2 0.0 0.0 0.0 3.0 1.7 0.0 0.0 0.0 7.7 100.0 722 0.1105 21.1 1.6 6.0 7.6 9.0 2.7 7.6 2.0 8.5 9.0 11.7 8.4 0.6 0.0 15.9 23.0 7.1 2.2 0.2 7.0 0.0 0.0 1.3 1.6 0.0 0.0 0.0 0.0 1.0 5.1 90.4 0.0 0.1 2.7 0.3 0.0 1.0 0.8 0.6 2.9 1.8 0.2 0.3 0.0 9.6 100.0 732 0.1102 18.4 2.4 5.9 8.3 10.7 0.0 5.5 2.9 8.9 7.1 10.6 7.1 0.0 0.0 22.5 33.2 10.7 2.1 0.0 10.7 0.0 0.0 1.3 0.8 0.1 0.0 0.0 0.0 0.9 4.7 92.1 0.1 0.0 2.3 0.0 0.1 1.2 0.8 0.9 2.4 1.4 0.0 0.0 0.0 7.9 100.0 742 0.1061 16.1 2.4 5.1 7.5 9.9 1.1 3.3 1.9 10.1 5.3 8.0 5.3 0.0 0.0 23.9 34.1 10.1 2.4 1.5 8.6 0.0 0.0 1.3 0.5 0.1 0.1 0.0 0.0 3.2 4.1 88.6 0.4 2.1 1.5 0.0 0.6 2.6 1.7 0.5 4.2 1.1 0.0 0.0 0.0 11.4 100.0 750 0.1169 15.6 2.5 5.3 7.8 10.2 0.9 3.6 2.8 9.8 5.4 8.1 5.2 0.0 0.2 23.6 33.2 9.6 2.5 0.6 9.1 0.3 0.0 1.2 0.2 0.1 0.1 0.0 0.2 3.2 4.2 88.8 0.5 1.7 1.5 0.0 0.7 2.7 1.8 0.6 4.2 1.0 0.1 0.0 0.0 11.2 100.0 765 0.1099 17.2 2.5 5.2 7.7 10.0 0.3 3.5 2.0 8.9 7.2 10.9 7.2 0.0 0.0 23.1 33.8 10.6 2.2 0.0 10.6 0.0 0.0 1.2 0.7 0.1 0.0 0.0 0.0 3.0 3.9 89.5 0.7 1.6 1.5 0.0 1.1 2.7 1.8 0.5 3.6 1.0 0.0 0.0 0.0 10.5 100.0