# Cariaco Basin, Venezuela, 600-kyr Scanning-XRF Sedimentary Mo Data
#-----------------------------------------------------------------------
#               World Data Center for Paleoclimatology, Boulder
#                                   and
#                      NOAA Paleoclimatology Program
#-----------------------------------------------------------------------
# NOTE: Please cite original publication, online resource and date accessed when using this data.
# If there is no publication information, please cite Investigator, title, online resource and date accessed.
#
# Description/Documentation lines begin with #
# Data lines have no #
#
# Online_Resource: http://www.ncdc.noaa.gov/paleo/study/16762
# Online_Resource: ftp://ftp.ncdc.noaa.gov/pub/data/paleo/contributions_by_author/gibson2014/gibson2014-d18o.txt
#
# Archive: Paleoceanography
#---------------------------------------
# Contribution_Date
#    Date: 2014-06-30
#---------------------------------------
# Title
#    Study_Name: Cariaco Basin, Venezuela, 600-kyr Scanning-XRF Sedimentary Mo Data
#---------------------------------------
# Investigators
#      Investigators: Gibson, Kelly A.; Peterson, Larry C.
#---------------------------------------
# Description and Notes
#        Description: This file contains the depth-age points used to construct the chronology for the spliced MD03-2622/ODP Hole 1002C scanning XRF record, the planktonic d18O record from ODP Hole 1002C, and the sedimentary Mo Scanning-XRF record from the spliced cores.
#---------------------------------------
# Publication
# Authors: Gibson, K.A. and L.C. Peterson
# Published_Date_or_Year: 2014
# Published_Title: A 0.6 Million Year Record of Millennial-Scale Climate Variability in the Tropics
# Journal_Name: Geophysical Research Letters
# Volume: 41
# Issue: 
# Pages: 969-975
# Report Number: 
# DOI: 10.1002/2013GL058846
# Abstract: A ~600 kyr long scanning X-ray fluorescence record of redox variability from the Cariaco Basin, Venezuela, provides insight into rapid climate change in the tropics over the past five glacial-interglacial cycles. Variations in the sediment accumulation of the redox-sensitive element molybdenum (Mo) can be linked to changes in Intertropical Convergence Zone migration and reveal that millennial-scale variability is a persistent feature of tropical climate over the past 600 kyr, including during periods of interglacial warmth. This geochemical record supports the idea that high-frequency tropical climate variability is not controlled solely by ice volume changes, with implications for the role of high-latitude forcing of Intertropical Convergence Zone position and tropical hydrology on millennial timescales.
#---------------------------------------
# Funding_Agency
#    Funding_Agency_Name: 
#    Grant: 
#---------------------------------------
# Site Information
# Site_Name: ODP1002
#  Location: North Atlantic Ocean, Cariaco Basin
#  Country:
# Northernmost_Latitude: 10.712167
# Southernmost_Latitude: 10.712167
# Easternmost_Longitude: -65.169667
# Westernmost_Longitude: -65.169667
# Elevation: -893
#---------------------------------------
# Data_Collection
#   Collection_Name: ODP1002C d18O G.ruber-w G14
#   First_Year: 582276
#   Last_Year: 1577
#   Time_Unit: cal yr BP
#   Core_Length: 
#   Notes: The oxygen isotope record comes entirely from ODP Site 1002 and used isotope ratio mass spectrometry. Depth in mbsf. 
#---------------------------------------
# Chronology: 
# The age model for MD03-2622 and for the upper 43 m of ODP Site 1002 was constructed by correlating their lightness (L*) records to the L* record of MD03-2621 on the NGRIP-based timescale of Deplazes et al. (2013) (see supplementary information accompanying the original publication for more details). The age model for ODP Hole 1002C below 43 mbsf was made by correlating a d18O record of the planktonic foraminifer Globigerinoides ruber (white morphotype) with the Lisiecki and Raymo (2005) benthic d18O stack using the program AnalySeries (Paillard et al., 1996). Note that depths listed refer to subbottom depths (m below sea floor) of tiepoints in MD03-2622 and ODP Site 1002, as indicated.  
# depth (mbsf)  age (ybp)  calibration
# 4.32  11675.7  MD03-2621/NGRIP
# 6.43  14683.2  MD03-2621/NGRIP
# 12.92  27280.6  MD03-2621/NGRIP
# 13.37  28319.5  MD03-2621/NGRIP
# 14.31  30504.1  MD03-2621/NGRIP
# 15.41  33275  MD03-2621/NGRIP
# 16.29  35557.3  MD03-2621/NGRIP
# 17.19  37418.8  MD03-2621/NGRIP  
# 18.8  41472.9  MD03-2621/NGRIP  
# 19.85  44282.3  MD03-2621/NGRIP  
# 21.63  49619.2  MD03-2621/NGRIP  
# 23.41  54826.5  MD03-2621/NGRIP  
# 24.05  55829.5  MD03-2621/NGRIP  
# 25.15  58670.3  MD03-2621/NGRIP  
# 25.72  59480.2  MD03-2621/NGRIP  
# 31.53  72169.63  MD03-2621/NGRIP  
# 32.8  76376.9  MD03-2621/NGRIP  
# 38.98  104072.07  MD03-2621/NGRIP  
# 44.3  127363.6  ODP Site 1002/LR05  
# 46.4  132282.1  ODP Site 1002/LR05  
# 56.1  166027.8  ODP Site 1002/LR05  
# 66.8  203611.9  ODP Site 1002/LR05   
# 75.4  236182.3  ODP Site 1002/LR05   
# 87  287054.1  ODP Site 1002/LR05   
# 96.1  333103.1  ODP Site 1002/LR05   
# 113.93  396085.44  ODP Site 1002/LR05   
# 136.05  490983.86  ODP Site 1002/LR05  
# 
#---------------------------------------
# Variables
# Data variables follow that are preceded by "##" in columns one and two.
# Variables list, one per line, shortname-tab-longname components (9 components: what, material, error, units, seasonality, archive, detail, method, C or N for Character or Numeric data)
## depth_m  depth,,,m ,,,,,N
## age_calyrBP  age,,,calendar years before 1950AD,,,,,N
## d18Og.rub-w.v	delta 18O,Globigerinoides ruber white,,per mil VPDB,,paleoceanography,,,N
# Data
# Data lines follow (have no #)
# Data line format - tab-delimited text, variable short name as header
# Missing Value: -999
depth_m	age_calyrBP	d18Og.rub-w.v
0.57	1577.63	-1.26
0.75	2075.83	-1.39
0.97	2684.74	-1.29
1.17	3238.30	-1.80
1.37	3791.86	-1.37
1.67	4622.19	-1.44
1.87	5175.74	-1.17
2.07	5729.30	-1.08
2.25	6227.50	-1.33
2.47	6836.41	-1.52
2.67	7389.97	-1.65
2.87	7943.52	-1.16
3.17	8732.21	-1.45
3.37	9244.12	-1.37
3.75	10216.75	-1.48
3.97	10779.86	-1.54
4.17	11291.77	-1.43
4.67	12189.16	-1.17
4.87	12482.56	-1.52
5.07	12775.33	-0.76
5.25	13027.84	0.01
5.47	13336.47	-0.04
5.67	13617.04	0.46
5.87	13897.61	0.30
6.07	14178.18	-0.27
6.37	14599.03	0.18
6.57	14903.79	0.40
6.97	15534.05	0.21
7.17	15849.18	0.06
7.37	16164.31	0.09
7.67	16637.00	-0.27
7.82	16909.98	-0.35
7.84	16950.65	-0.44
8.07	17418.34	0.48
8.57	18435.07	0.71
8.76	18821.42	0.27
8.96	19228.12	0.53
9.12	19553.47	0.54
9.35	20021.16	0.70
9.54	20407.52	0.78
9.74	20814.21	0.62
10.03	21403.91	0.33
10.23	21810.60	1.01
10.42	22196.96	0.86
10.59	22542.65	0.72
10.81	22990.01	0.67
11.01	23396.70	0.32
11.20	23783.06	0.62
11.50	24393.09	0.43
11.69	24779.45	0.33
11.89	25186.14	0.59
12.05	25511.49	0.76
12.28	25979.19	0.74
12.47	26365.54	0.58
12.67	26772.24	0.85
12.96	27354.04	0.41
13.16	27721.26	0.44
13.35	28257.76	0.46
13.52	28730.96	0.83
13.74	29256.76	0.41
13.94	29694.43	0.52
14.13	30110.20	-0.26
14.42	30803.72	0.11
14.62	31348.47	0.38
14.81	31865.99	0.08
14.98	32329.04	0.21
15.21	32855.39	0.36
15.40	33254.02	0.15
15.60	33766.10	0.56
15.89	34518.79	0.39
16.08	35012.08	0.56
16.28	35531.34	0.29
16.45	35869.71	0.18
16.67	36299.27	0.06
16.87	36708.48	-0.34
17.06	37130.23	-0.01
17.35	37915.54	-0.02
17.40	38070.77	-0.27
17.55	38466.51	0.16
17.97	39476.66	0.26
18.06	39693.12	0.03
18.16	39933.63	-0.42
18.63	41064.03	-0.17
18.73	41304.54	-0.16
19.11	42220.48	-0.17
19.21	42461.63	0.33
19.30	42678.67	-0.02
19.40	42919.83	0.08
19.49	43136.87	0.13
19.59	43378.02	-0.09
19.69	43685.20	0.41
19.78	44021.07	0.24
19.97	44660.83	-0.53
20.04	44881.63	0.11
20.16	45260.16	0.47
20.35	45859.50	0.33
20.54	46458.83	0.03
20.72	47012.14	-0.28
20.93	47613.77	-0.26
21.02	47871.61	0.03
21.47	49160.82	0.19
21.69	49807.43	0.45
21.79	50121.16	0.33
21.88	50403.51	-0.17
21.98	50717.23	0.44
22.07	50999.58	0.40
22.29	51689.77	0.15
22.39	52003.49	0.65
22.48	52285.85	0.67
22.58	52599.57	0.77
22.67	52881.92	0.82
22.76	53164.27	0.59
22.86	53477.99	0.65
22.93	53697.60	0.38
23.06	54105.44	0.15
23.15	54337.53	0.23
23.25	54525.59	0.39
23.34	54694.85	-0.37
23.53	55104.12	0.40
23.60	55266.07	0.55
23.82	55547.07	-0.26
24.01	55780.38	0.30
24.11	55979.43	0.45
24.20	56204.32	0.26
24.30	56454.19	0.35
24.36	56604.12	0.12
24.49	56928.96	-0.16
24.58	57153.85	0.75
24.68	57403.73	0.31
24.77	57628.62	0.73
24.87	57878.50	-0.11
24.97	58128.37	-0.47
25.19	58719.77	-0.46
25.28	58831.07	-0.10
25.38	58954.73	0.81
25.47	59083.53	0.26
25.57	59242.20	0.14
25.76	59568.25	0.97
25.95	59986.49	0.48
26.04	60184.60	0.49
26.14	60404.72	0.69
26.24	60624.85	0.46
26.33	60822.96	0.46
26.43	61043.08	0.47
26.51	61219.18	0.97
26.62	61461.32	0.87
26.72	61681.45	0.91
26.90	62077.67	0.75
27.00	62297.80	0.29
27.09	62495.91	0.88
27.47	63332.38	0.57
27.56	63530.49	0.88
27.75	63948.73	0.35
27.85	64168.85	1.08
27.94	64366.97	0.88
28.10	64719.17	-0.07
28.19	64917.28	0.42
28.40	65379.54	-0.05
28.61	65841.80	0.64
28.70	66039.91	1.12
28.80	66260.04	0.67
28.89	66458.15	0.13
28.99	66678.28	-0.09
29.08	66876.39	-0.12
29.18	67096.51	0.83
29.27	67294.62	0.99
29.53	67866.95	0.64
29.65	68131.10	0.55
29.84	68549.34	0.77
29.94	68769.46	1.08
30.03	68967.57	0.62
30.13	69187.70	0.61
30.20	69341.78	0.48
30.35	69671.97	0.83
30.44	69870.08	0.80
30.54	70090.21	0.61
30.63	70288.32	0.35
30.73	70497.35	0.38
30.82	70685.49	0.31
30.98	71019.94	0.13
31.11	71291.69	-0.05
31.20	71479.82	-0.24
31.30	71688.85	0.13
31.39	71876.98	0.14
31.49	72086.02	0.36
31.58	72359.84	0.38
31.68	72740.27	0.55
31.84	73348.95	0.72
31.93	73691.33	0.40
32.03	74033.70	-0.07
32.12	74307.58	-0.25
32.22	74611.89	-0.50
32.31	74885.77	-0.46
32.45	75311.81	-0.17
32.60	75768.28	-0.46
32.69	76042.16	-0.76
32.79	76346.47	-0.14
32.88	76651.51	0.24
33.07	77303.69	0.24
33.15	77578.30	0.22
33.37	78333.47	0.32
33.46	78642.40	-0.27
33.56	78985.66	-0.56
33.65	79294.59	-0.86
33.75	79637.85	-0.70
33.84	79946.78	-0.57
33.97	80393.01	-0.29
34.13	80942.22	-0.71
34.22	81251.15	-0.51
34.32	81594.41	-0.57
34.41	81903.34	-0.30
34.51	82246.60	-0.34
34.60	82555.53	-0.66
34.70	82898.79	-0.27
34.82	83310.70	-0.38
34.91	83619.63	-0.61
35.01	83962.89	-1.32
35.10	84271.82	-1.02
35.20	84615.08	-0.83
35.29	85010.66	0.11
35.46	85888.83	0.30
35.58	86508.72	-0.08
35.67	86973.63	0.30
35.77	87490.20	0.08
35.86	87955.11	-0.10
35.96	88471.68	0.02
36.05	88936.59	0.19
36.15	89453.16	0.02
36.24	89918.07	0.05
36.35	90486.30	0.03
36.43	90899.55	-0.21
36.52	91364.47	-0.16
36.65	92036.01	-0.74
36.93	93482.40	-0.27
37.06	94153.94	-0.77
37.15	94618.85	-0.35
37.24	95083.77	-0.50
37.34	95600.33	-0.38
37.43	96065.25	-0.58
37.52	96530.16	-0.26
37.60	96943.41	-0.45
37.71	97511.64	-0.31
37.80	97976.55	-0.26
37.90	98493.12	-0.72
37.99	98958.03	-0.46
38.08	99422.95	-0.52
38.18	99939.52	-0.54
38.25	100301.11	-0.58
38.36	100869.34	-1.01
38.45	101334.25	-1.05
38.55	101850.82	-0.44
38.62	102212.42	-0.55
38.76	102935.62	-0.69
38.81	103193.90	-0.75
38.92	103762.13	-0.89
39.00	104151.01	-0.35
39.11	104585.18	-0.27
39.18	104861.46	-0.12
39.30	105335.10	-0.20
39.37	105611.39	-0.27
39.48	106045.56	-1.05
39.56	106361.31	-1.27
39.67	106795.48	-0.59
39.76	107150.71	-0.96
39.86	107545.41	-0.67
39.95	107900.63	-0.52
40.04	108255.86	-0.48
40.14	108693.83	0.17
40.23	109097.75	0.03
40.32	109501.66	-0.32
40.40	109860.69	0.03
40.51	110354.37	-0.12
40.60	110758.28	-0.43
40.69	111162.19	-0.34
40.79	111610.98	-0.30
40.88	112014.90	-0.58
40.97	112418.81	-0.26
41.04	112732.97	-0.26
41.23	113585.67	-0.66
41.32	113989.58	-0.53
41.41	114393.50	-0.71
41.51	114842.29	-0.79
41.60	115246.20	-0.86
41.69	115650.12	-0.77
41.79	116098.91	-0.74
41.86	116413.06	-1.18
41.97	116906.74	-1.06
42.06	117310.65	-0.89
42.18	117849.20	-0.91
42.25	118163.35	-0.99
42.34	118567.27	-0.79
42.44	119016.06	-0.76
42.52	119375.09	-0.98
42.62	119823.89	-0.94
42.72	120272.68	-1.22
42.81	120676.59	-0.84
42.90	121080.51	-0.57
43.00	121529.30	-0.86
43.09	121933.21	-1.10
43.18	122337.12	-1.31
43.26	122696.16	-1.39
43.37	123189.83	-1.03
43.46	123593.74	-1.21
43.56	124042.54	-1.73
43.65	124446.45	-0.96
43.74	124850.36	-1.19
43.84	125299.15	-1.44
43.89	125523.55	-1.49
44.02	126106.98	-1.53
44.12	126555.77	-1.47
44.21	126959.69	-1.19
44.31	127386.44	-0.78
44.40	127592.03	-0.67
44.49	127797.62	-0.45
44.58	128003.21	-0.56
44.66	128185.96	-0.56
44.77	128437.24	-0.54
44.86	128642.83	-0.40
45.32	129705.76	-0.88
45.42	129944.31	-0.99
45.70	130612.25	-0.72
45.79	130826.95	-0.93
45.99	131304.05	-0.87
46.15	131685.73	-0.13
46.56	132843.44	0.08
46.69	133299.53	0.69
46.90	134036.28	0.68
46.99	134352.04	0.51
47.17	134983.54	0.70
47.27	135334.38	0.69
47.33	135544.88	0.74
47.45	135965.88	0.74
47.54	136281.64	0.62
47.63	136597.39	0.72
47.73	136948.23	0.46
47.82	137263.98	0.82
47.96	137755.15	0.48
48.09	138211.24	0.77
48.19	138562.07	0.81
48.28	138877.83	0.59
48.37	139193.58	0.69
48.46	139509.33	0.62
48.55	139825.08	0.86
48.65	140175.92	1.10
48.70	140351.34	0.69
48.83	140807.43	0.81
48.92	141123.18	0.71
49.01	141438.93	0.92
49.12	141824.85	0.94
49.25	142280.94	0.94
49.35	142631.78	0.75
49.43	142912.45	0.82
49.53	143263.28	0.76
49.62	143579.04	0.68
49.71	143894.79	0.75
49.81	144245.62	0.65
49.98	144842.05	0.13
50.08	145192.88	0.89
50.17	145508.64	0.77
50.27	145859.47	0.96
50.36	146175.23	0.58
50.45	146490.98	1.02
50.51	146701.48	0.50
50.63	147122.48	0.87
50.76	147578.57	0.62
50.84	147859.24	0.80
51.00	148420.58	0.81
51.09	148736.33	0.77
51.19	149087.17	0.85
51.37	149718.67	0.92
51.45	149999.34	1.09
51.56	150385.26	0.91
51.65	150701.02	0.83
51.74	151016.77	0.95
51.82	151297.44	0.93
51.91	151613.19	1.01
52.06	152139.45	0.96
52.14	152420.12	1.00
52.25	152806.04	0.43
52.34	153121.79	0.83
52.40	153332.29	1.16
52.52	153753.29	1.04
52.61	154069.05	1.09
52.80	154727.24	0.29
52.89	155035.44	0.12
52.98	155343.64	0.81
53.07	155651.83	1.07
53.17	155994.27	0.39
53.26	156302.47	0.42
53.32	156507.94	0.59
53.49	157090.09	0.59
53.56	157329.79	0.65
53.67	157706.48	0.69
53.76	158014.68	0.40
53.86	158357.12	0.59
53.95	158665.31	0.71
54.04	158973.51	0.37
54.14	159315.95	0.20
54.22	159589.91	0.23
54.32	159932.35	0.36
54.41	160240.54	0.01
54.50	160548.74	0.53
54.59	160856.94	0.09
54.68	161165.14	-0.12
54.78	161507.58	0.17
54.85	161747.29	0.05
54.96	162123.97	-0.01
55.05	162432.17	0.03
55.15	162774.61	0.56
55.20	162945.83	0.87
55.33	163391.00	0.77
55.41	163664.96	0.68
55.55	164144.37	0.70
55.97	165582.63	0.27
56.05	165856.58	0.49
56.13	166131.85	-0.52
56.22	166444.00	-0.40
56.30	166721.47	0.06
56.39	167033.62	-0.21
56.47	167311.09	-0.01
56.53	167519.20	-0.29
56.61	167796.66	-0.29
56.71	168143.50	0.37
56.80	168455.65	0.55
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