New Caledonia Coral Stable Isotope Data --------------------------------------------------------------------- NOAA Paleoclimatology Program and World Data Center for Paleoclimatology --------------------------------------------------------------------- NOTE: PLEASE CITE ORIGINAL REFERENCE WHEN USING THIS DATA!!!!! NAME OF DATA SET: New Caledonia Coral Stable Isotope Data LAST UPDATE: 8/1995 (Original Receipt by WDCA Paleo) CONTRIBUTORS: Quinn, T.M., Taylor, F.W., Crowley, T.C., and Link, S. IGBP PAGES/WDCA Data Contribution Series #: 1998-008 SUGGESTED DATA CITATION: Quinn, T.M., Taylor, F.W., Crowley, T.C., and Link, S., 1998, New Caledonia Coral Stable Isotope Data. IGBP PAGES/World Data Center-A for Paleoclimatology, Data Contribution Series # 1998-008. NOAA/NGDC Paleoclimatology Program, Boulder CO, USA. ORIGINAL REFERENCE: Quinn, T.M., Taylor, F.W., Crowley, T.C., and Link, S., 1996, Evaluation of Sampling Resolution in Coral Stable Isotope Records: A Case Study Using Monthly Stable Isotope Records from New Caledonia and Tarawa; Paleoceanography, v. 11, n. 5, 529-542. GEOGRAPHIC REGION: Equatorial Pacific PERIOD OF RECORD: 1956- 1996 AD DESCRIPTION: Coral Site: Amedee Lighthouse, New Caledonia (22°S, 167°E) Coral Species: Porites lutea Sampling Resolution: 1.03 mm/sample Sampling technique: Sequential routing or milling Special Note: Sample numbers 137-140, 293-300, are 326-330 do not exist. Abstract We have generated a 40-year-long, monthly stable isotope record from a Porites lutea coral collected offshore of Amedee, New Caledonia (22°S, 167°E) to investigate the relation between sampling resolution in coral isotope studies and retrieval of sea-surface environmental information. We interpret the high correlation between our oxygen isotope record and a twenty-year long sea-surface temperature record at the monthly timescale (r=0.88) to indicate that our coral isotope record is an accurate monitor of environmental conditions offshore of Amedee. The character of the signal and the percent variance explained in the record at the annual band, at the quasi-biennial oscillation band ((QBO) 2.0-2.4 years), and at the El Nino-Southern Oscillation band ((ENSO) 3-8 years) changes little in response to a reduction in sampling density from monthly to bimonthly to quarterly. Similar results have been obtained in a reanalysis of a coral isotope record from Tarawa, Kiribati. Our results indicate that a significant amount of the information obtained from high-density sampling can also be retrieved from lower-density sampling. In particular, bimonthly sampling yields virtually no drop-off in variance explained, and quarterly sampling is satisfactory for resolving interannual and decadal-scale trends in time series. The proposed sampling approach may enable a more rapid filling in of numerous spatial holes in coral sampling sites needed for reconstruction of long-term decadal-scale variations in climate. Methods Coral Sampling We drilled a ~3.45-m-long, 4.5-cm-diameter core nearly down the vertical axis of maximum growth of the Porites lutea coral head in July 1992 near the lighthouse on Amedee Island, New Caledonia. This sample was collected alive at ~3 m water depth, less than a few hundred meters from the location of the daily SST and SSS measurements. The coral was slabbed to a thickness of 5 mm. X-radiographs of the coral slab were taken under exposure conditions of 55 kV, 3 mA, with an exposure time of 20 s. X-radiographs revealed highly regular and well-developed annual density bands. Physical sampling of the coral skeleton is initially guided by the position of a density-band couplet. Hence sampling resolution is often initially defined as the number of samples per density-band couplet (samples/dbc). Forty density- band couplets were observed to occur in 49.25 cm in our New Caledonia coral, yielding an average annual growth rate for this 40-year period of 1.23 cm/year. Growth rate varied from a low 1.08 cm/year to a high of 1.32 cm/year during this interval. We sampled the coral slab at a resolution of 1.03 mm/sample, which yielded 12 samples/dbc (i.e., we drilled and removed powder every 1.03 mm). Drill bit diameter was 1 mm and sample depth was 0.5 mm. The sampling device used in this study was a computer-aided triaxial sampler (CATS). In this device, the hand- held portion of a dentist's drill is clamped in a small vise which is bolted to the movable base of the sampler; the latter is inclined at ~30° from horizontal and controls the in and out movement of the sample. The coral slab is held in place on a motorized stage that is oriented perpendicular to the base, and this stage controls the up and down movement of the sample. The stage that holds the coral slab is itself attached at 90° to a third motorized stage which controls the right to left movement of the sample. The starting and ending coordinates along with the depth and length of each drilled interval are input to the software program that runs the sampling device. Sampling of corals usually involves a sample length on the order of millimeters; however, the CATS device can be used to sample on the order of tens of microns. Used in the fashion described above, the CATS device generates a series of continuously routed samples along a straight pathway, although sampling along curved pathways is also possible (e.g., mollusc shells). Stable Isotope Analyses We generated a 40-year-long stable isotope record to produce a sufficient number of annual and interannual cycles so that we could perform statistical and spectral analyses with the data. Stable isotopic analyses were performed at the University of Michigan. Prior to isotopic analysis, powdered coralline aragonite samples were vacuum roasted for 1 hour at 200°C. Samples were reacted with anhydrous phosphoric acid at 75°C in individual reaction vessels of a CarboKiel carbonate-extraction system coupled to the inlet of a MAT 251 mass spectrometer. Precision (±1 ?) was monitored by daily analyses of a powdered calcite standard (NBS-20) and was better than 0.04‰ for both oxygen and carbon. The average standard deviation of 46 replicate analyses of coral samples is 0.10‰ for oxygen and 0.07‰ carbon. Values are reported in standard ? notation relative to the Chicago Pee Dee belemnite (PDB) standard after correction for the 17O contribution. Sample Sequential Actual Sampling Coral Coral Path Sample # Sample # mm 13C 18O 1 1 1 1.03 -2.16 -4.28 1 2 2 2.06 -1.87 -4.21 1 3 3 3.09 -1.69 -4.30 1 4 4 4.12 -1.72 -4.52 1 5 5 5.15 -1.54 -4.64 1 6 6 6.18 -1.32 -4.71 1 7 7 7.21 -1.42 -4.79 1 8 8 8.24 -1.34 -4.69 1 9 9 9.27 -1.42 -4.44 1 10 10 10.3 -1.27 -4.24 1 11 11 11.33 -1.52 -4.15 1 12 12 12.36 -1.50 -4.16 1 13 13 13.39 -1.54 -4.31 1 14 14 14.42 -1.21 -4.41 1 15 15 15.45 -1.02 -4.68 1 16 16 16.48 -1.27 -4.72 1 17 17 17.51 -1.52 -4.62 1 18 18 18.54 -1.42 -4.50 1 19 19 19.57 -1.62 -4.27 1 20 20 20.6 -1.64 -4.12 1 21 21 21.63 -1.78 -4.23 1 22 22 22.66 -1.73 -4.32 1 23 23 23.69 -1.71 -4.49 1 24 24 24.72 -1.37 -4.68 1 25 25 25.75 -1.30 -4.93 1 26 26 26.78 -1.17 -4.73 1 27 27 27.81 -1.30 -4.73 1 28 28 28.84 -1.32 -4.59 1 29 29 29.87 -1.28 -4.57 1 30 30 30.9 -1.37 -4.25 1 31 31 31.93 -1.38 -4.13 1 32 32 32.96 -1.48 -4.49 1 33 33 33.99 -1.78 -4.67 1 34 34 35.02 -1.56 -4.64 1 35 35 36.05 -1.34 -4.73 1 36 36 37.08 -2.02 -4.72 1 37 37 38.11 -2.40 -4.65 1 38 38 39.14 -1.46 -4.23 1 39 39 40.17 -1.35 -4.19 1 40 40 41.2 -1.47 -4.21 1 41 41 42.23 -1.57 -4.40 1 42 42 43.26 -1.42 -4.49 1 43 43 44.29 -1.52 -4.49 1 44 44 45.32 -1.09 -4.50 1 45 45 46.35 -0.94 -4.33 1 46 46 47.38 -1.04 -4.03 1 47 47 48.41 -1.00 -3.96 1 48 48 49.44 -1.55 -4.16 1 49 49 50.47 -0.94 -4.26 1 50 50 51.5 -1.14 -4.66 1 51 51 52.53 -1.30 -4.60 1 52 52 53.56 -1.19 -4.43 1 53 53 54.59 -1.18 -4.43 1 54 54 55.62 -1.11 -4.34 1 55 55 56.65 -1.08 -3.93 1 56 56 57.68 -1.05 -4.04 1 57 57 58.71 -1.29 -4.23 1 58 58 59.74 -1.39 -4.23 1 59 59 60.77 -1.31 -4.44 1 60 60 61.8 -1.43 -4.75 1 61 61 62.83 -1.60 -4.79 1 62 62 63.86 -1.50 -4.65 1 63 63 64.89 -1.60 -4.82 1 64 64 65.92 -1.32 -4.44 1 65 65 66.95 -1.06 -4.19 1 66 66 67.98 -1.18 -3.82 1 67 67 69.01 -1.10 -3.91 1 68 68 70.04 -1.67 -4.02 1 69 69 71.07 -1.35 -4.37 1 70 70 72.1 -1.17 -4.70 1 71 71 73.13 -1.36 -4.43 1 72 72 74.16 -1.27 -4.72 1 73 73 75.19 -1.30 -4.73 1 74 74 76.22 -1.03 -4.76 1 75 75 77.25 -1.16 -4.42 1 76 76 78.28 -1.18 -4.11 1 77 77 79.31 -1.18 -4.06 1 78 78 80.34 -1.10 -3.91 1 79 79 81.37 -1.09 -3.93 1 80 80 82.4 -1.24 -4.26 1 81 81 83.43 -1.41 -4.51 1 82 82 84.46 -1.51 -4.65 1 83 83 85.49 -1.20 -4.61 1 84 84 86.52 -1.23 -4.62 1 85 85 87.55 -1.35 -4.41 1 86 86 88.58 -1.31 -4.41 1 87 87 89.61 -0.86 -4.19 1 88 88 90.64 -0.75 -3.98 1 89 89 91.67 -0.93 -4.19 1 90 90 92.7 -0.96 -4.31 1 91 91 93.73 -1.54 -4.54 1 92 92 94.76 -1.48 -4.86 1 93 93 95.79 -1.14 -4.78 1 94 94 96.82 -1.25 -4.79 1 95 95 97.85 -1.25 -4.77 1 96 96 98.88 -1.39 -4.75 1 97 97 99.91 -1.14 -4.50 1 98 98 100.94 -0.91 -4.27 1 99 99 101.97 -0.79 -3.91 1 100 100 103 -0.96 -4.04 1 101 101 104.03 -1.33 -4.32 1 102 102 105.06 -1.14 -4.52 1 103 103 106.09 -1.23 -4.78 1 104 104 107.12 -1.38 -4.82 1 105 105 108.15 -1.05 -4.71 1 106 106 109.18 -1.34 -4.63 1 107 107 110.21 -1.22 -4.31 1 108 108 111.24 -1.22 -4.08 1 109 109 112.27 -1.17 -4.01 1 110 110 113.3 -1.27 -4.05 1 111 111 114.33 -1.33 -4.05 1 112 112 115.36 -1.03 -4.44 1 113 113 116.39 -1.32 -4.79 1 114 114 117.42 -1.11 -4.81 1 115 115 118.45 -1.04 -4.83 1 116 116 119.48 -1.29 -4.79 1 117 117 120.51 -1.31 -4.48 "1,2" 118 "118,141" 121.54 -1.32 -4.39 "1,2" 119 "119,142" 122.57 -1.10 -4.27 "1,2" 120 "120,143" 123.6 -1.09 -4.05 "1,2" 121 "121,144" 124.63 -1.01 -3.93 "1,2" 122 "122,145" 125.66 -1.24 -4.15 "1,2" 123 "123,146" 126.69 -1.24 -4.33 "1,2" 124 "124,147" 127.72 -1.30 -4.50 "1,2" 125 "125,148" 128.75 -1.36 -4.64 "1,2" 126 "126,149" 129.78 -1.43 -4.88 "1,2" 127 "127,150" 130.81 -1.40 -4.92 "1,2" 128 "128,151" 131.84 -1.48 -4.78 "1,2" 129 "129,152" 132.87 -1.38 -4.63 "1,2" 130 "130,153" 133.9 -1.12 -4.43 "1,2" 131 "131,154" 134.93 -1.01 -4.11 "1,2" 132 "132,155" 135.96 -0.88 -3.91 "1,2" 133 "133,156" 136.99 -0.95 -3.89 "1,2" 134 "134,157" 138.02 -1.09 -4.10 "1,2" 135 "135,158" 139.05 -1.22 -4.33 "1,2" 136 "136,159" 140.08 -2.12 -4.55 2 137 160 141.11 -0.67 -4.62 2 138 161 142.14 -1.01 -4.60 2 139 162 143.17 -1.18 -4.50 2 140 163 144.2 -1.13 -4.42 2 141 164 145.23 -1.16 -4.12 2 142 165 146.26 -0.92 -3.95 2 143 166 147.29 -1.26 -3.99 2 144 167 148.32 -1.17 -4.39 2 145 168 149.35 -1.21 -4.50 2 146 169 150.38 -1.25 -4.78 2 147 170 151.41 -1.24 -4.60 2 148 171 152.44 -1.20 -4.68 2 149 172 153.47 -2.02 -5.36 2 150 173 154.5 -1.45 -4.36 2 151 174 155.53 -1.11 -4.13 2 152 175 156.56 -1.08 -4.06 2 153 176 157.59 -1.61 -4.30 2 154 177 158.62 -1.21 -4.40 2 155 178 159.65 -1.14 -4.56 2 156 179 160.68 -1.20 -4.79 2 157 180 161.71 -1.16 -4.83 2 158 181 162.74 -1.23 -4.82 2 159 182 163.77 -1.53 -4.73 2 160 183 164.8 -0.90 -4.38 2 161 184 165.83 -0.95 -4.05 2 162 185 166.86 -1.07 -4.11 2 163 186 167.89 -1.51 -4.38 2 164 187 168.92 -1.65 -4.59 2 165 188 169.95 -1.47 -4.74 2 166 189 170.98 -1.63 -5.05 2 167 190 172.01 -1.24 -5.11 2 168 191 173.04 -1.32 -4.94 2 169 192 174.07 -1.30 -4.81 2 170 193 175.1 -1.47 -4.70 2 171 194 176.13 -1.29 -4.49 2 172 195 177.16 -0.95 -4.42 2 173 196 178.19 -0.83 -4.11 2 174 197 179.22 -1.00 -4.05 2 175 198 180.25 -1.16 -4.21 2 176 199 181.28 -1.45 -4.57 2 177 200 182.31 -1.70 -4.67 2 178 201 183.34 -1.07 -4.80 2 179 202 184.37 -1.14 -4.64 2 180 203 185.4 -1.06 -4.64 2 181 204 186.43 -1.22 -4.62 2 182 205 187.46 -1.16 -4.52 2 183 206 188.49 -1.22 -4.23 2 184 207 189.52 -1.28 -4.71 2 185 208 190.55 -0.96 -3.91 2 186 209 191.58 -1.24 -4.05 2 187 210 192.61 -1.43 -4.29 2 188 211 193.64 -1.17 -4.47 2 189 212 194.67 -1.28 -4.71 2 190 213 195.7 -1.06 -4.85 2 191 214 196.73 -1.13 -4.84 2 192 215 197.76 -1.22 -4.99 2 193 216 198.79 -1.24 -4.90 2 194 217 199.82 -1.01 -4.64 2 195 218 200.85 -0.95 -4.51 2 196 219 201.88 -1.10 -4.42 2 197 220 202.91 -0.75 -4.06 2 198 221 203.94 -0.82 -4.08 2 199 222 204.97 -1.30 -4.23 2 200 223 206 -1.16 -4.31 2 201 224 207.03 -1.40 -4.46 2 202 225 208.06 -1.14 -4.41 2 203 226 209.09 -0.94 -4.70 2 204 227 210.12 -1.60 -4.93 2 205 228 211.15 -1.41 -4.89 2 206 229 212.18 -1.71 -4.85 2 207 230 213.21 -1.52 -4.70 2 208 231 214.24 -1.45 -4.55 2 209 232 215.27 -1.10 -4.37 2 210 233 216.3 -1.04 -4.05 2 211 234 217.33 -0.99 -3.96 2 212 235 218.36 -0.85 -4.11 2 213 236 219.39 -1.07 -4.38 2 214 237 220.42 -1.14 -4.57 2 215 238 221.45 -1.25 -4.77 2 216 239 222.48 -1.29 -4.99 2 217 240 223.51 -0.98 -4.83 2 218 241 224.54 -1.17 -4.71 2 219 242 225.57 -1.30 -4.64 2 220 243 226.6 -1.30 -4.58 2 221 244 227.63 -1.14 -4.60 2 222 245 228.66 -1.14 -4.32 2 223 246 229.69 -0.96 -4.11 2 224 247 230.72 -0.98 -3.98 2 225 248 231.75 -1.26 -4.33 2 226 249 232.78 -1.04 -4.59 2 227 250 233.81 -1.33 -4.62 2 228 251 234.84 -1.64 -4.75 2 229 252 235.87 -1.70 -4.79 2 230 253 236.9 -1.72 -5.01 2 231 254 237.93 -1.17 -4.84 2 232 255 238.96 -1.36 -4.64 2 233 256 239.99 -1.45 -4.38 2 234 257 241.02 -1.40 -4.20 2 235 258 242.05 -1.39 -4.12 2 236 259 243.08 -0.98 -4.00 2 237 260 244.11 -1.16 -4.00 2 238 261 245.14 -1.22 -4.19 2 239 262 246.17 -1.52 -4.44 2 240 263 247.2 -1.83 -4.60 2 241 264 248.23 -1.55 -4.51 2 242 265 249.26 -1.23 -4.78 2 243 266 250.29 -1.19 -4.79 2 244 267 251.32 -1.10 -4.74 2 245 268 252.35 -1.07 -4.75 2 246 269 253.38 -1.14 -4.63 2 247 270 254.41 -1.02 -4.47 2 248 271 255.44 -1.12 -4.24 2 249 272 256.47 -0.83 -4.07 2 250 273 257.5 -0.83 -4.09 2 251 274 258.53 -1.04 -4.21 2 252 275 259.56 -1.30 -4.49 "2,3" 253 "276,301" 260.59 -1.14 -4.62 "2,3" 254 "277,302" 261.62 -1.29 -4.73 "2,3,4" 255 "278,303,331" 262.65 -1.26 -4.73 "2,3,4" 256 "279,304,332" 263.68 -1.29 -4.73 "2,3,4" 257 "280,305,333" 264.71 -1.49 -4.68 "2,3,4" 258 "281,306,334" 265.74 -1.52 -4.56 "2,3,4" 259 "282,307,335" 266.77 -1.26 -4.50 "2,3,4" 260 "283,308,336" 267.8 -1.24 -4.34 "2,3,4" 261 "284,309,337" 268.83 -1.06 -4.08 "2,3,4" 262 "285,310,338" 269.86 -1.13 -3.99 "2,3,4" 263 "286,311,339" 270.89 -1.13 -4.03 "2,3,4" 264 "287,312,340" 271.92 -1.46 -4.31 "2,3,4" 265 "288,313,341" 272.95 -1.32 -4.35 "2,3,4" 266 "289,314,342" 273.98 -1.22 -4.62 "2,3,4" 267 "290,315,343" 275.01 -1.49 -4.74 "2,3,4" 268 "291,316,344" 276.04 -1.32 -4.78 "2,3,4" 269 "292,317,345" 277.07 -1.33 -4.65 3 270 318 278.1 -1.62 -4.52 3 271 319 279.13 -1.59 -4.49 "3,4" 272 "320,346" 280.16 -1.36 -4.37 "3,4" 273 "321,347" 281.19 -1.27 -4.27 "3,4" 274 "322,348" 282.22 -1.22 -4.07 "3,4" 275 "323,349" 283.25 -1.11 -4.03 "3,4" 276 "324,350" 284.28 -0.99 -3.83 4 277 325 285.31 -1.11 -3.72 4 278 351 286.34 -1.18 -3.89 4 279 352 287.37 -1.60 -4.22 4 280 353 288.4 -1.67 -4.40 4 281 354 289.43 -1.16 -4.47 4 282 355 290.46 -1.21 -4.59 4 283 356 291.49 -1.12 -4.56 4 284 357 292.52 -1.24 -4.46 4 285 358 293.55 -0.59 -4.17 4 286 359 294.58 -0.38 -3.89 4 287 360 295.61 -0.54 -3.77 4 288 361 296.64 -1.19 -4.04 4 289 362 297.67 -0.99 -4.26 4 290 363 298.7 -1.24 -4.38 4 291 364 299.73 -1.24 -4.58 4 292 365 300.76 -1.18 -4.54 4 293 366 301.79 -0.99 -4.55 4 294 367 302.82 -1.29 -4.61 4 295 368 303.85 -1.65 -4.51 4 296 369 304.88 -1.20 -4.27 4 297 370 305.91 -0.97 -4.21 4 298 371 306.94 -1.00 -4.00 4 299 372 307.97 -1.23 -4.17 4 300 373 309 -1.79 -4.38 4 301 374 310.03 -1.85 -4.55 4 302 375 311.06 -1.81 -4.64 4 303 376 312.09 -1.57 -4.80 4 304 377 313.12 -1.49 -4.77 4 305 378 314.15 -1.32 -4.80 4 306 379 315.18 -1.27 -4.71 4 307 380 316.21 -1.22 -4.60 4 308 381 317.24 -1.12 -4.47 4 309 382 318.27 -1.08 -4.25 4 310 383 319.3 -0.97 -4.11 4 311 384 320.33 -1.12 -3.93 4 312 385 321.36 -1.19 -4.00 4 313 386 322.39 -1.61 -4.28 4 314 387 323.42 -1.82 -4.54 4 315 388 324.45 -1.60 -4.54 4 316 389 325.48 -1.72 -4.79 4 317 390 326.51 -1.52 -4.88 4 318 391 327.54 -1.19 -4.76 4 319 392 328.57 -1.30 -4.70 4 320 393 329.6 -1.42 -4.65 4 321 394 330.63 -1.31 -4.48 4 322 395 331.66 -1.20 -4.40 4 323 396 332.69 -1.04 -4.30 4 324 397 333.72 -0.74 -3.99 4 325 398 334.75 -0.69 -3.85 4 326 399 335.78 -1.25 -4.13 4 327 400 336.81 -1.47 -4.35 4 328 401 337.84 -1.68 -4.50 4 329 402 338.87 -1.63 -4.69 4 330 403 339.9 -1.53 -4.95 4 331 404 340.93 -1.78 -5.05 4 332 405 341.96 -1.88 -4.99 4 333 406 342.99 -1.74 -4.84 4 334 407 344.02 -1.37 -4.80 4 335 408 345.05 -1.27 -4.66 4 336 409 346.08 -0.56 -4.14 4 337 410 347.11 -0.59 -3.97 4 338 411 348.14 -0.87 -3.99 4 339 412 349.17 -1.34 -4.24 4 340 413 350.2 -1.57 -4.48 4 341 414 351.23 -1.55 -4.65 4 342 415 352.26 -1.32 -4.71 4 343 416 353.29 -1.21 -4.81 4 344 417 354.32 -1.07 -4.74 4 345 418 355.35 -1.44 -4.54 4 346 419 356.38 -1.55 -4.57 4 347 420 357.41 -1.29 -4.42 4 348 421 358.44 -1.30 -4.39 4 349 422 359.47 -1.23 -4.33 4 350 423 360.5 -1.08 -4.13 4 351 424 361.53 -0.78 -4.00 4 352 425 362.56 -1.05 -4.08 4 353 426 363.59 -1.38 -4.25 4 354 427 364.62 -1.71 -4.41 4 355 428 365.65 -1.68 -4.50 4 356 429 366.68 -1.57 -4.43 4 357 430 367.71 -1.53 -4.60 4 358 431 368.74 -1.49 -4.78 4 359 432 369.77 -1.51 -4.77 4 360 433 370.8 -1.45 -4.60 4 361 434 371.83 -1.56 -4.53 4 362 435 372.86 -0.70 -4.44 4 363 436 373.89 -0.65 -4.10 4 364 437 374.92 -1.13 -4.02 4 365 438 375.95 -1.13 -4.01 4 366 439 376.98 -1.56 -3.94 4 367 440 378.01 -1.70 -4.25 4 368 441 379.04 -1.64 -4.34 4 369 442 380.07 -1.68 -4.71 4 370 443 381.1 -1.18 -4.66 4 371 444 382.13 -1.01 -4.66 4 372 445 383.16 -1.41 -4.61 4 373 446 384.19 -1.40 -4.58 4 374 447 385.22 -1.27 -4.58 4 375 448 386.25 -0.83 -4.28 4 376 449 387.28 -1.12 -4.48 4 377 450 388.31 -0.98 -4.11 4 378 451 389.34 -1.12 -4.27 4 379 452 390.37 -1.19 -4.38 4 380 453 391.4 -1.28 -4.54 4 381 454 392.43 -1.46 -4.61 4 382 455 393.46 -1.39 -4.75 4 383 456 394.49 -1.25 -4.93 4 384 457 395.52 -1.64 -4.86 4 385 458 396.55 -1.34 -4.75 4 386 459 397.58 -1.31 -4.61 4 387 460 398.61 -1.26 -4.44 4 388 461 399.64 -1.08 -4.39 4 389 462 400.67 -1.01 -4.17 4 390 463 401.7 -0.86 -4.13 4 391 464 402.73 -0.75 -3.96 4 392 465 403.76 -1.18 -4.25 4 393 466 404.79 -1.14 -4.21 4 394 467 405.82 -1.34 -4.68 4 395 468 406.85 -1.16 -4.81 4 396 469 407.88 -1.35 -4.88 4 397 470 408.91 -1.20 -5.02 4 398 471 409.94 -1.25 -4.95 4 399 472 410.97 -1.29 -4.87 4 400 473 412 -1.21 -4.79 4 401 474 413.03 -1.03 -4.57 4 402 475 414.06 -1.39 -4.99 4 403 476 415.09 -1.37 -4.14 4 404 477 416.12 -1.36 -4.25 4 405 478 417.15 -1.39 -4.30 4 406 479 418.18 -1.48 -4.56 4 407 480 419.21 -1.59 -4.57 4 408 481 420.24 -0.39 -4.02 4 409 482 421.27 -1.58 -5.12 4 410 483 422.3 -0.79 -4.08 4 411 484 423.33 -1.40 -4.94 4 412 485 424.36 -1.41 -4.58 4 413 486 425.39 -1.25 -5.00 4 414 487 426.42 -1.41 -5.11 4 415 488 427.45 -1.14 -4.68 4 416 489 428.48 -0.93 -4.68 4 417 490 429.51 -0.93 -4.07 4 418 491 430.54 -0.74 -4.07 4 419 492 431.57 -1.48 -4.76 4 420 493 432.6 -0.79 -4.08 4 421 494 433.63 -1.22 -4.87 4 422 495 434.66 -1.15 -4.54 4 423 496 435.69 -1.38 -4.78 4 424 497 436.72 -0.78 -4.06 4 425 498 437.75 -1.24 -4.54 4 426 499 438.78 -1.36 -4.52 4 427 500 439.81 -1.04 -4.35 4 428 501 440.84 -1.48 -4.68 4 429 502 441.87 -0.36 -3.66 4 430 503 442.9 -1.71 -5.11 4 431 504 443.93 -1.25 -4.31 4 432 505 444.96 -1.19 -4.88 4 433 506 445.99 -1.44 -5.13 4 434 507 447.02 -1.23 -4.58 4 435 508 448.05 -0.97 -4.69 4 436 509 449.08 -0.87 -4.20 4 437 510 450.11 -0.88 -4.36 4 438 511 451.14 -1.14 -4.26 4 439 512 452.17 -0.93 -3.92 4 440 513 453.2 -1.60 -4.58 4 441 514 454.23 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