Zaca Lake, California 3000 Year Leaf Wax dD and Modern Vegetation Data Feakins, S.J.; Kirby, M.E.; Cheetham, M.I.; Ibarra, Y.; Zimmerman, S.R.H. Feakins, S.J. Kirby, M.E. Cheetham, M.I. Ibarra, Y. Zimmerman, S.R.H. earth science/paleoclimate/paleolimnology (delta 2H,C28 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C34 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C34 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C22 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid; compounded standard deviation) earth science/paleoclimate/paleolimnology (delta 2H,C28 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid; compounded standard deviation) earth science/paleoclimate/paleolimnology (C28 n-alkanoic acid,null,null,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (delta 2H,C24 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid) earth science/paleoclimate/paleolimnology (delta 2H,C30 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid; compounded standard deviation) earth science/paleoclimate/paleolimnology (delta 2H,C34 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid; compounded standard deviation) earth science/paleoclimate/paleolimnology (C22 n-alkanoic acid,null,one standard deviation,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (depth,null,null,centimeter,null,paleolimnology,null,null,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C26 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (C32 n-alkanoic acid,null,null,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (C32 n-alkanoic acid,null,one standard deviation,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (modal chain length,n-alkanoic acid,null,count,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C30 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C26 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid; compounded standard deviation) earth science/paleoclimate/paleolimnology (delta 2H,C32 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid; compounded standard deviation) earth science/paleoclimate/paleolimnology (C24 n-alkanoic acid,null,one standard deviation,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (delta 2H,C24 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C24 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C26 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid) earth science/paleoclimate/paleolimnology (C28 n-alkanoic acid,null,one standard deviation,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (delta 2H,C32 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C34 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid) earth science/paleoclimate/paleolimnology (C22 n-alkanoic acid,null,null,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (C30 n-alkanoic acid,null,null,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (C26 n-alkanoic acid,null,one standard deviation,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (carbon preference index,n-alkanoic acid,null,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C22 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C22 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C28 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C30 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C32 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C22 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid) earth science/paleoclimate/paleolimnology (delta 2H,C32 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid) earth science/paleoclimate/paleolimnology (C24 n-alkanoic acid,null,null,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (C30 n-alkanoic acid,null,one standard deviation,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (age,null,null,calendar year before present,null,paleolimnology,null,null,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C26 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (delta 2H,C28 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid) earth science/paleoclimate/paleolimnology (delta 2H,C30 n-alkanoic acid,null,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid) earth science/paleoclimate/paleolimnology (delta 2H,C24 n-alkanoic acid,one standard deviation,per mil VSMOW,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,fractionation between water and C-acid; compounded standard deviation) earth science/paleoclimate/paleolimnology (C26 n-alkanoic acid,null,null,dimensionless,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,Relative abundance for chain length i calculated where Ci/[SC22-30 even n-alkanoic acids]) earth science/paleoclimate/paleolimnology (average chain length,n-alkanoic acid,null,count,null,paleolimnology,null,gas chromatography|isotope ratio mass spectrometry,N,null) earth science/paleoclimate/paleolimnology (Zaca Lake>LATITUDE 34.77778>LONGITUDE -120.0392) The hydrogen isotopic composition of plant molecular markers in modern vegetation and marine sediments in southern California have been intensively studied. Here we report a late Holocene reconstruction from Zaca Lake in coastal southern California, together with modern hydrological and vegetation studies in the catchment. The small catchment and decadal sampling resolution throughout the 9 m, 3000 yr sedimentary record provided a high resolution terrigenous counterpart of nearby marine records from the Santa Barbara Basin. Today, dD values of precipitation average -51.5‰ ± 18 (1sigma, n = 7). Modern plant leaf wax dD values for the C28n-alkanoic acid averaged -141‰ ± 11 (1sigma, n = 10) for Quercus agrifolia, with a calculated fractionation relative to precipitation (Ewax/precip) of -94‰ ± 22 (1sigma, n = 10); in contrast, there was negligible production of the C28 acid by co-dominant Pinus coulteri. Downcore, the C28 acid dD values ranged between -101‰ and -177‰ (mean -150‰ ± 8, 1sigma, n = 490). Abundance distributions suggested that the sedimentary C28 acid was dominated by Quercus, implying that paleoprecipitation varied between extremes of −8‰ and −92‰ (mean −63‰ ± 14, compound 1σ, n = 490). The 3000 yr leaf wax D/H record from Zaca Lake revealed substantial temporal variability, greater than observed in a speleothem reconstruction of similar resolution. We suggest that the plant-based proxy may magnify the variability by sampling spring precipitation preferentially. Centennial-duration positive isotopic excursions were associated with more sub-tropical moisture sources and drier conditions including during the Medieval Climatic Anomaly, and negative excursions were associated with N Pacific sources and wetter conditions including during the Little Ice Age. STUDY NOTES: Zaca Lake, Southern coastal California sediment leaf wax hydrogen isotopic composition data spanning the last 3000 years. Age model from radiocarbon and historical datums including appearance of pollen of non-native species. Leaf wax D/H is used to reconstruct hydroclimate changes including changes in moisture source regions. Modern vegetation in the catchment are also studied to provide context for the downcore record. Data from Zaca Lake core 1C (USC-ZACA09-1C), 8.2 Ha lake area, 12m water depth. This record extends to 872cm depth and 2932 years. NCDC-Paleoclimatology https://www.ncdc.noaa.gov/data-access/paleoclimatology-data - Bauer Bruce Investigator : Feakins, S.J. Investigator : Kirby, M.E. Investigator : Cheetham, M.I. Investigator : Ibarra, Y. Investigator : Zimmerman, S.R.H. 2013-11-27 ONLINE Files online, ASCII https://www.ncdc.noaa.gov/paleo/study/15634 https://www1.ncdc.noaa.gov/pub/data/paleo/paleolimnology/northamerica/usa/california/zaca2014.txt https://www1.ncdc.noaa.gov/pub/data/paleo/paleolimnology/northamerica/usa/california/zaca2014.xls https://www1.ncdc.noaa.gov/pub/data/paleo/paleolimnology/northamerica/usa/california/zaca2014.txt https://www1.ncdc.noaa.gov/pub/data/paleo/paleolimnology/northamerica/usa/california/zaca2014.xls English https://www.ncdc.noaa.gov/paleo/study/15634 https://www1.ncdc.noaa.gov/pub/data/paleo/paleolimnology/northamerica/usa/california/zaca2014.txt https://www1.ncdc.noaa.gov/pub/data/paleo/paleolimnology/northamerica/usa/california/zaca2014.xls Sarah J. Feakins, Matthew E. Kirby, Michael I. Cheetham, Yadira Ibarra, Susan R.H. Zimmerman2014Fluctuation in leaf wax D/H ratio from a southern California lake records significant variability in isotopes in precipitation during the late HoloceneOrganic Geochemistry6648-5910.1016/j.orggeochem.2013.10.015http://www.sciencedirect.com/science/article/pii/S0146638013002428 START YEAR: 2932 cal yr BP * END YEAR: -58 cal yr BP -120.0392 34.77778 -120.0392 34.77778