<DIF xmlns="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/ http://gcmd.gsfc.nasa.gov/Aboutus/xml/dif/dif_v9.8.4.xsd">
  <Entry_ID>noaa-cave-12194</Entry_ID>
  <Entry_Title>Northern Spain 4000 Year Stalagmite d13C and Temperature Reconstruction </Entry_Title>
  <Data_Set_Citation>
    <Dataset_Creator>Martín-Chivelet, J.; Muñoz-García, M.B.; Edwards, R.L.; Turrero, M.J.; Ortega, A.I.</Dataset_Creator>
    <Dataset_Title>Northern Spain 4000 Year Stalagmite d13C and Temperature Reconstruction </Dataset_Title>
    <Dataset_Release_Date>2011-09-26</Dataset_Release_Date>
    <Dataset_Publisher>NCDC-Paleoclimatology</Dataset_Publisher>
    <Data_Presentation_Form>ONLINE Files</Data_Presentation_Form>
    <Dataset_DOI>Pending</Dataset_DOI>
    <Online_Resource>https://www.ncdc.noaa.gov/paleo/study/12194</Online_Resource>
  </Data_Set_Citation>
  <Personnel>
    <Role>Investigator</Role>
    <First_Name>J.</First_Name>
    <Last_Name>Martín-Chivelet</Last_Name>
  </Personnel>
  <Personnel>
    <Role>Investigator</Role>
    <First_Name>M.B.</First_Name>
    <Last_Name>Muñoz-García</Last_Name>
  </Personnel>
  <Personnel>
    <Role>Investigator</Role>
    <First_Name>R.L.</First_Name>
    <Last_Name>Edwards</Last_Name>
  </Personnel>
  <Personnel>
    <Role>Investigator</Role>
    <First_Name>M.J.</First_Name>
    <Last_Name>Turrero</Last_Name>
  </Personnel>
  <Personnel>
    <Role>Investigator</Role>
    <First_Name>A.I.</First_Name>
    <Last_Name>Ortega</Last_Name>
  </Personnel>
  <Parameters>
    <Category>earth science</Category>
    <Topic>paleoclimate</Topic>
    <Term>climate reconstructions|speleothems</Term>
    <Detailed_Variable>surface air temperature,delta 13C,null,degree Celsius,annual,climate reconstructions|speleothems,anomalized,null,N,null</Detailed_Variable>
  </Parameters>
  <Parameters>
    <Category>earth science</Category>
    <Topic>paleoclimate</Topic>
    <Term>climate reconstructions|speleothems</Term>
    <Detailed_Variable>age,null,null,calendar year before present,null,climate reconstructions|speleothems,null,null,N,null</Detailed_Variable>
  </Parameters>
  <Parameters>
    <Category>earth science</Category>
    <Topic>paleoclimate</Topic>
    <Term>speleothems</Term>
    <Detailed_Variable>sample identification,null,null,null,null,speleothems,null,null,C,null</Detailed_Variable>
  </Parameters>
  <Parameters>
    <Category>earth science</Category>
    <Topic>paleoclimate</Topic>
    <Term>climate reconstructions|speleothems</Term>
    <Detailed_Variable>surface air temperature,delta 13C,null,degree Celsius,annual,climate reconstructions|speleothems,anomalized|smoothed,null,N,10 year running mean</Detailed_Variable>
  </Parameters>
  <Parameters>
    <Category>earth science</Category>
    <Topic>paleoclimate</Topic>
    <Term>climate reconstructions|speleothems</Term>
    <Detailed_Variable>age,null,null,year Common Era,null,climate reconstructions|speleothems,null,null,N,null</Detailed_Variable>
  </Parameters>
  <Parameters>
    <Category>earth science</Category>
    <Topic>paleoclimate</Topic>
    <Term>speleothems</Term>
    <Detailed_Variable>delta 13C,calcium carbonate,null,standard deviation unit,null,speleothems,anomalized,isotope ratio mass spectrometry,N,anomalized relative to 380-1280 CE</Detailed_Variable>
  </Parameters>
  <Parameters>
    <Category>earth science</Category>
    <Topic>paleoclimate</Topic>
    <Term>speleothems</Term>
    <Variable_Level_1>carbon isotopes</Variable_Level_1>
  </Parameters>
  <ISO_Topic_Category>geoscientificInformation</ISO_Topic_Category>
  <Keyword>Air Temperature Reconstruction</Keyword>
  <Paleo_Temporal_Coverage>
    <Paleo_Start_Date>-1949 AD</Paleo_Start_Date>
    <Paleo_Stop_Date>2000 AD</Paleo_Stop_Date>
  </Paleo_Temporal_Coverage>
  <Paleo_Temporal_Coverage>
    <Paleo_Start_Date>3899 cal yr BP</Paleo_Start_Date>
    <Paleo_Stop_Date>-50 cal yr BP</Paleo_Stop_Date>
  </Paleo_Temporal_Coverage>
  <Data_Set_Progress>Complete</Data_Set_Progress>
  <Spatial_Coverage>
    <Southernmost_Latitude>42.3481</Southernmost_Latitude>
    <Northernmost_Latitude>43.04</Northernmost_Latitude>
    <Westernmost_Longitude>-4.3728</Westernmost_Longitude>
    <Easternmost_Longitude>-3.5164</Easternmost_Longitude>
    <Minimum_Altitude>860</Minimum_Altitude>
    <Maximum_Altitude>1640</Maximum_Altitude>
  </Spatial_Coverage>
  <Location>
    <Location_Category>Continent</Location_Category>
    <Location_Type>Europe</Location_Type>
    <Location_Subregion1>Southern Europe</Location_Subregion1>
    <Location_Subregion2>Spain</Location_Subregion2>
    <Detailed_Location>Kaite Cave&gt;LATITUDE 43.04&gt;LONGITUDE -3.6597</Detailed_Location>
  </Location>
  <Location>
    <Location_Category>Continent</Location_Category>
    <Location_Type>Europe</Location_Type>
    <Location_Subregion1>Southern Europe</Location_Subregion1>
    <Location_Subregion2>Spain</Location_Subregion2>
    <Detailed_Location>Cueva del Cobre&gt;LATITUDE 42.9872&gt;LONGITUDE -4.3728</Detailed_Location>
  </Location>
  <Location>
    <Location_Category>Continent</Location_Category>
    <Location_Type>Europe</Location_Type>
    <Location_Subregion1>Southern Europe</Location_Subregion1>
    <Location_Subregion2>Spain</Location_Subregion2>
    <Detailed_Location>Cueva Mayor&gt;LATITUDE 42.3481&gt;LONGITUDE -3.5164</Detailed_Location>
  </Location>
  <Access_Constraints>None</Access_Constraints>
  <Use_Constraints>Please cite original publication, online resource, dataset and publication DOIs (where available), and date accessed when using downloaded data. If there is no publication information, please cite investigator, title, online resource, and date accessed. The appearance of external links associated with a dataset does not constitute endorsement by the Department of Commerce/National Oceanic and Atmospheric Administration of external Web sites or the information, products or services contained therein. For other than authorized activities, the Department of Commerce/NOAA does not exercise any editorial control over the information you may find at these locations. These links are provided consistent with the stated purpose of this Department of Commerce/NOAA Web site.</Use_Constraints>
  <Data_Set_Language>English</Data_Set_Language>
  <Data_Center>
    <Data_Center_Name>
      <Short_Name>DOC/NOAA/NESDIS/NCEI</Short_Name>
      <Long_Name>National Centers for Environmental Information, NESDIS, NOAA, U.S. Department of Commerce </Long_Name>
    </Data_Center_Name>
    <Data_Center_URL>https://www.ncdc.noaa.gov/data-access/paleoclimatology-data</Data_Center_URL>
    <Personnel>
      <Role>DATA Center Contact</Role>
      <First_Name>Bruce</First_Name>
      <Last_Name>Bauer</Last_Name>
      <Email>bruce.a.bauer@noaa.gov</Email>
      <Email>paleo@noaa.gov</Email>
      <Phone>303-497-6280</Phone>
      <Fax>303-497-6513</Fax>
      <Contact_Address>
        <Address>325 Broadway, E/NE31</Address>
        <City>Boulder</City>
        <Province_or_State>CO</Province_or_State>
        <Postal_Code>80305-3328</Postal_Code>
        <Country>USA</Country>
      </Contact_Address>
    </Personnel>
  </Data_Center>
  <Distribution>
    <Distribution_Media>online</Distribution_Media>
    <Distribution_Format>ASCII</Distribution_Format>
  </Distribution>
  <Reference>Martín-Chivelet, J., M.B. Muñoz-García, R.L. Edwards, M.J. Turrero, 
and A.I. Ortega. 2011. 
Land surface temperature changes in Northern Iberia since 4000 yr BP, 
based on d13C of speleothems. 
Global and Planetary Change, Vol. 77, Issues 1-2, May 2011, pp. 1-12.  
doi:10.1016/j.gloplacha.2011.02.002. </Reference>
  <Summary>
    <Abstract>The surface temperature changes for the last 4000 years in northern 
inland Iberia (an area particularly sensitive to climate change) 
are determined by a high resolution study of carbon stable isotope 
records of stalagmites from three caves (Kaite, Cueva del Cobre, 
and Cueva Mayor) separated several tens of kilometers away in N Spain. 
Despite the local conditions of each cave, the isotopic series show 
a good overall coherence, and resulted to be strongly sensitive to 
surface temperature changes.  The record reflects alternating warmer 
and colder intervals, always within a temperature range of 1.6 °C. 
The timing and duration of the intervals were provided by 43 
230Th-234U (ICP-MS) ages. Main climatic recognized periods are: 
(1) 3950-3000 yr BP: warm period punctuated by cool events around 
~3950, 3550 and 3250 yr BP; (2) 2850-2500 yr BP cold interval 
(Iron Age Cold Period); (3) 2500-1650 yr BP moderate warm period 
(Roman Warm Period), with maximum temperatures between 2150 and 
1750 yr BP; (4) 1650-1350 yr BP cold interval (Dark Ages Cold Period), 
with a thermal minimum at ~1500 yr BP; (5) 1350-750 yr BP warm period 
(Medieval Warm Period) punctuated by two cooler events at ~1250 and 
~850 yr BP; (6) 750-100 yr BP cold period (Little Ice Age) with 
extremes occurring at 600-500 yr BP, 350-300 yr BP, and 150100 yr BP; 
and (7) the last 150 years, characterized by rapid but no linear 
warming (Modern Warming).  Remarkably, the presented records allow 
direct comparison of recent warming with former warm intervals 
such as the Roman or the Medieval periods. That comparison reveals 
the 20th century as the time with highest surface temperatures 
of the last 4000 years for the studied area.  Spectral analysis 
of the time series shows consistent climatic cycles of ~400, 
~900 and ~1300 yr, comparable with those recognized in the 
North Atlantic marine record, the Greenland ice cores, and other 
terrestrial records for the middle-late Holocene, suggesting common 
climate forcing mechanisms related to changes in solar irradiance 
and North Atlantic circulation patterns. 
 
          STUDY NOTES: Carbon stable isotope stacked series for the last 4000 years 
derived from three stalagmites of three caves of N Spain 
(Kaite, Cobre, and Cueva Mayor). Age model is based in 43 230Th 
absolute ages. Analyses for age-dating were conducted at the 
University of Minnesota by means of ICP-MS. Carbon isotope data 
are expressed as absolute deviation values i.e., the absolute 
difference between that each d13C(V-PDB) value and a reference 
value for each stalagmite. This reference value is the average 
d13C of each stalagmite for the time interval between 1570 
and 670 yr BP - the longest interval of continuous and 
simultaneous growing of the three stalagmites.  For each 
measurement, approximately 100ug of powder sample were drilled 
from petrographical thin sections of the axial part of the 
stalagmites, and analyzed with an on-line, automated, carbonate 
preparation system (Kiel III), linked to a Finnigan MAT-252 ratio 
mass spectrometer at the University of Minnesota Isotope Lab. 
The 13C data is translated into relative temperature estimates 
by means of a transfer function based in cross correlation 
between instrumental series of temperatures and d13C values 
in stalagmite SLX1 (estimated error ±0.26 °C). 

</Abstract>
  </Summary>
  <Related_URL>
    <URL_Content_Type>
      <Type>GET DATA</Type>
    </URL_Content_Type>
    <URL>https://www1.ncdc.noaa.gov/pub/data/paleo/speleothem/europe/spain/nspain2011d13ct.xls</URL>
  </Related_URL>
  <Related_URL>
    <URL_Content_Type>
      <Type>GET DATA</Type>
    </URL_Content_Type>
    <URL>https://www1.ncdc.noaa.gov/pub/data/paleo/speleothem/europe/spain/nspain2011d13ct.txt</URL>
  </Related_URL>
  <IDN_Node>
    <Short_Name>USA/NOAA</Short_Name>
  </IDN_Node>
  <Metadata_Name>DIF</Metadata_Name>
  <Metadata_Version>Version 9.8.4</Metadata_Version>
  <DIF_Creation_Date>2018-12-11</DIF_Creation_Date>
  <Last_DIF_Revision_Date>2018-12-11</Last_DIF_Revision_Date>
</DIF>
