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ABSTRACT SUPPLIED BY ORIGINATOR: Global climate and the concentration of atmospheric carbon dioxide (CO2) are correlated over recent glacial cycles. The combination of processes responsible for a rise in atmospheric CO2 at the last glacial termination (23,000 to 9,000 years ago), however, remains uncertain. Establishing the timing and rate of CO2 changes in the past provides critical insight into the mechanisms that influence the carbon cycle and helps put present and future anthropogenic emissions in context. Here we present CO2 and methane (CH4) records of the last deglaciation from a new high-accumulation West Antarctic ice core with unprecedented temporal resolution and precise chronology. We show that although low-frequency CO2 variations parallel changes in Antarctic temperature, abrupt CO2 changes occur that have a clear relationship with abrupt climate changes in the Northern Hemisphere. A significant proportion of the direct radiative forcing associated with the rise in atmospheric CO2 occurred in three sudden steps, each of 10 to 15 parts per million. Every step took place in less than two centuries and was followed by no notable change in atmospheric CO2 for about 1,000 to 1,500 years. Slow, millennial-scale ventilation of Southern Ocean CO2-rich, deep-ocean water masses is thought to have been fundamental to the rise in atmospheric CO2 associated with the glacial termination, given the strong covariance of CO2 levels and Antarctic temperatures. Our data establish a contribution from an abrupt, centennial-scale mode of CO2 variability that is not directly related to Antarctic temperature. We suggest that processes operating on centennial timescales, probably involving the Atlantic meridional overturning circulation, seem to be influencing global carbon-cycle dynamics and are at present not widely considered in Earth system models.</gco:CharacterString>
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            <gco:CharacterString>1-828-271-4800</gco:CharacterString>
           </gmd:voice>
           <gmd:facsimile>
            <gco:CharacterString>1-828-271-4876</gco:CharacterString>
           </gmd:facsimile>
          </gmd:CI_Telephone>
         </gmd:phone>
         <gmd:address>
          <gmd:CI_Address>
           <gmd:deliveryPoint>
            <gco:CharacterString>151 Patton Avenue</gco:CharacterString>
           </gmd:deliveryPoint>
           <gmd:deliveryPoint>
            <gco:CharacterString>Veach-Baley Federal Building, Room 468</gco:CharacterString>
           </gmd:deliveryPoint>
           <gmd:city>
            <gco:CharacterString>Asheville</gco:CharacterString>
           </gmd:city>
           <gmd:administrativeArea>
            <gco:CharacterString>NC</gco:CharacterString>
           </gmd:administrativeArea>
           <gmd:postalCode>
            <gco:CharacterString>28801-5001</gco:CharacterString>
           </gmd:postalCode>
           <gmd:country>
            <gco:CharacterString>USA</gco:CharacterString>
           </gmd:country>
           <gmd:electronicMailAddress>
            <gco:CharacterString>ncei.orders@noaa.gov</gco:CharacterString>
           </gmd:electronicMailAddress>
          </gmd:CI_Address>
         </gmd:address>
         <gmd:onlineResource>
          <gmd:CI_OnlineResource>
           <gmd:linkage>
            <gmd:URL>https://www.ncei.noaa.gov</gmd:URL>
           </gmd:linkage>
           <gmd:protocol>
            <gco:CharacterString>HTTPS</gco:CharacterString>
           </gmd:protocol>
           <gmd:applicationProfile>
            <gco:CharacterString>Web Browser</gco:CharacterString>
           </gmd:applicationProfile>
           <gmd:name>
            <gco:CharacterString>NOAA National Centers for Environmental Information (NCEI)</gco:CharacterString>
           </gmd:name>
           <gmd:description>
            <gco:CharacterString>NCEI home page with information, data access and contact information.</gco:CharacterString>
           </gmd:description>
           <gmd:function>
            <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
           </gmd:function>
          </gmd:CI_OnlineResource>
         </gmd:onlineResource>
         <gmd:hoursOfService>
          <gco:CharacterString>8:00 - 6:00 Eastern</gco:CharacterString>
         </gmd:hoursOfService>
        </gmd:CI_Contact>
       </gmd:contactInfo>
       <gmd:role>
        <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="distributor">distributor</gmd:CI_RoleCode>
       </gmd:role>
      </gmd:CI_ResponsibleParty>
     </gmd:distributorContact>
     <gmd:distributionOrderProcess>
      <gmd:MD_StandardOrderProcess>
       <gmd:fees>
        <gco:CharacterString>In most cases, electronic downloads of the data are free, however fees may apply for data certifications, copies of analog materials, and data distribution on physical media.</gco:CharacterString>
       </gmd:fees>
      </gmd:MD_StandardOrderProcess>
     </gmd:distributionOrderProcess>
     <gmd:distributorFormat>
      <gmd:MD_Format>
       <gmd:name>
        <gco:CharacterString>Native Format(s)</gco:CharacterString>
       </gmd:name>
       <gmd:version gco:nilReason="missing"></gmd:version>
      </gmd:MD_Format>
     </gmd:distributorFormat>
     <gmd:distributorTransferOptions>
      <gmd:MD_DigitalTransferOptions>
       <gmd:onLine>
        <gmd:CI_OnlineResource>
         <gmd:linkage>
          <gmd:URL>https://data.nodc.noaa.gov/cgi-bin/iso?id=noaa-icecore-18636</gmd:URL>
         </gmd:linkage>
         <gmd:protocol>
          <gco:CharacterString>HTTPS</gco:CharacterString>
         </gmd:protocol>
         <gmd:applicationProfile>
          <gco:CharacterString>Landing Page</gco:CharacterString>
         </gmd:applicationProfile>
         <gmd:name>
          <gco:CharacterString>NCEI landing page for this dataset</gco:CharacterString>
         </gmd:name>
         <gmd:description>
          <gco:CharacterString>Dataset landing page with general information and links to access the data.</gco:CharacterString>
         </gmd:description>
         <gmd:function>
          <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
         </gmd:function>
        </gmd:CI_OnlineResource>
       </gmd:onLine>
       <gmd:onLine>
        <gmd:CI_OnlineResource>
         <gmd:linkage>
          <gmd:URL>https://www.ncdc.noaa.gov/paleo/study/18636</gmd:URL>
         </gmd:linkage>
         <gmd:protocol>
          <gco:CharacterString>HTTPS</gco:CharacterString>
         </gmd:protocol>
         <gmd:applicationProfile>
          <gco:CharacterString>Web Browser</gco:CharacterString>
         </gmd:applicationProfile>
         <gmd:name>
          <gco:CharacterString>NCEI Study Page</gco:CharacterString>
         </gmd:name>
         <gmd:description>
          <gco:CharacterString>Study page with dataset access information.</gco:CharacterString>
         </gmd:description>
         <gmd:function>
          <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="search">search</gmd:CI_OnLineFunctionCode>
         </gmd:function>
        </gmd:CI_OnlineResource>
       </gmd:onLine>
       <gmd:onLine>
        <gmd:CI_OnlineResource>
         <gmd:linkage>
          <gmd:URL>https://www.ncdc.noaa.gov/data-access/paleoclimatology-data/datasets/ice-core</gmd:URL>
         </gmd:linkage>
         <gmd:protocol>
          <gco:CharacterString>HTTPS</gco:CharacterString>
         </gmd:protocol>
         <gmd:applicationProfile>
          <gco:CharacterString>Information</gco:CharacterString>
         </gmd:applicationProfile>
         <gmd:name>
          <gco:CharacterString>NCEI Ice Core Page</gco:CharacterString>
         </gmd:name>
         <gmd:description>
          <gco:CharacterString>General information for this data type.</gco:CharacterString>
         </gmd:description>
         <gmd:function>
          <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
         </gmd:function>
        </gmd:CI_OnlineResource>
       </gmd:onLine>
       <gmd:onLine>
        <gmd:CI_OnlineResource>
         <gmd:linkage>
          <gmd:URL>https://www1.ncdc.noaa.gov/pub/data/paleo/icecore/antarctica/wais2014co2.txt</gmd:URL>
         </gmd:linkage>
         <gmd:protocol>
          <gco:CharacterString>HTTP</gco:CharacterString>
         </gmd:protocol>
         <gmd:applicationProfile>
          <gco:CharacterString>Download</gco:CharacterString>
         </gmd:applicationProfile>
         <gmd:name>
          <gco:CharacterString>NCEI Direct Download</gco:CharacterString>
         </gmd:name>
         <gmd:description>
          <gco:CharacterString>Direct download links for dataset files.</gco:CharacterString>
         </gmd:description>
         <gmd:function>
          <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
         </gmd:function>
        </gmd:CI_OnlineResource>
       </gmd:onLine>
      </gmd:MD_DigitalTransferOptions>
     </gmd:distributorTransferOptions>
    </gmd:MD_Distributor>
   </gmd:distributor>
  </gmd:MD_Distribution>
 </gmd:distributionInfo>
 <gmd:metadataMaintenance>
  <gmd:MD_MaintenanceInformation>
   <gmd:maintenanceAndUpdateFrequency>
    <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
   </gmd:maintenanceAndUpdateFrequency>
   <gmd:maintenanceNote>
    <gco:CharacterString>This metadata record was translated from DIF using dif-9x-to-iso-19115-2.xsl Version: 2018-10-25</gco:CharacterString>
   </gmd:maintenanceNote>
  </gmd:MD_MaintenanceInformation>
 </gmd:metadataMaintenance>
</gmi:MI_Metadata>