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    <gco:CharacterString>STUDY NOTES: Concentration and D-alloisoleucine/L-isoleucine values from mixed foraminfera samples from sediment cores from Atlantic, Caribbean, and Pacific basins. Core Locations: Core Latitude Longitude WaterDepth(m) OceanBasin V12-122 17.00 -74.47 2730 A A179-4 16.60 -74.80 2965 A V16-205 15.40 -43.40 4045 A V16-39 -24.72 -4.75 4510 A V12-18 -28.70 -34.50 2935 A RC8-93 -29.37 -105.23 3157 P V23-110 17.63 -45.87 3746 A CH96-G12 30.27 -43.32 4014 A V24-28 15.32 -77.95 2274 A RC5-12 26.58 -56.48 5104 A A167-21 29.82 -76.58 1455 A V18 BBD 2 -17.93 -154.13 800 P JOIDES Leg 7, site 62-1 1.867 141.93 2591 P Leg 7, site 64-1 -1.73 158.60 2052 P Leg 6, site 47-2 32.45 157.72 2689 P LABORTAORY AND ANALYTICAL INFORMATION Lab history Lamont-Doherty Geological Observatory (LDGO) and Carnegie Institution of Washington, Geophysical Laboratory (GL CIW) Lab PI J. F. Wehmiller and P. E. Hare Preparation date 1969-1970 Pretreatment Sieve &gt;74 µm, repeated sonication, distilled water wash (see &quot;Sonication&quot;) AA fraction = AMINO FRACTION Hydrolysis procedure 22 or 46 hr at 110°C in 6 M HCl under N2 (see &quot;Hydrolysis time&quot;) Bleach No Analytical method High pressure ion exchange liquid chromatography (IELC) Instrumental programming Buffer gradient; concentrations based on separate chromatograms of standards Area or height ratio Area Blank corrections none Response factors none Data screening criteria none Interlab comparisons none SAMPLE LOCATION INFORMATION Country or ocean Atlantic, Pacific State or province or sea Caribbean Locality descriptors = AREA Lat (°) = LAT (°N) Lon (°) = LON (°W) Coordinate precision Datum Elevation, m = WATER DEPTH (m) Elevation precision SAMPLE MATERIAL AND CONTEXT Material type = SAMPLE TYPE Genus Species Number of individuals Field context marine Field context core Field context stratified section Collection date Collector Wehmiller Sample PI Wehmiller Stratigraphic unit or age Numerical age = APPROX AGE, Ma Field ID = SITE NAME Field ID 1 = CORE DEPTH (cm) Field ID 2 Sample ID Fraction of shell Sample position RESULTS Lab code GL CIW Lab ID = Core, depth Number of chromatograms 1 Sample or analytical qualitsee reference AI = Alloisoleucine/Isoleucine Free field 1 = Alloisoleucine, nmole/gm Free field 2 = Isoleucine, nmole/gm Free field 3 = Hydrolysis time Free field 4 = Sonication 
ABSTRACT SUPPLIED BY ORIGINATOR: Isoleucine, one of several amino acids isolated from a suite of well-dated deep-sea cores, shows a progressive increase in the degree of racemization with the age of the sediment. Amino acids in sediments show an initial rate of racemization almost an order of magnitude faster than the rate observed for free amino acids at a comparable pH and temperature. The observed kinetics depend on a variety of diagenetic processes, but it appears that the ratio of alloisoleucine to isoleucine is a reliable indicator of age for samples less than 400,000 years old; for older samples the results are more ambiguous. Isoleucine is racemic in samples older than about 15 million years.</gco:CharacterString>
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