# Cueva de Asiul, Spain 12,000 Year Speleothem Oxygen Isotope Data 
#----------------------------------------------------------------------- 
#                World Data Service for Paleoclimatology, Boulder 
#                                  and 
#                     NOAA Paleoclimatology Program 
#             National Centers for Environmental Information (NCEI)
#----------------------------------------------------------------------- 
#
# NOTE: Please cite original publication, online resource and date accessed when using this data.
# If there is no publication information, please cite Investigator, title, online resource and date accessed.
#
# Description/Documentation lines begin with #
# Data lines have no #
#
# Online_Resource: http://www.ncdc.noaa.gov/paleo/study/20082
# Online_Resource: http://www1.ncdc.noaa.gov/pub/data/paleo/speleothem/europe/spain/asiul2016composite.txt
#
# Archive: Speleothems
#
# Parameter_Keywords: oxygen isotopes, geochemistry
#---------------------------------------
# Contribution_Date
#    Date: 2016-04-25
#---------------------------------------
# Title
#    Study_Name: Cueva de Asiul, Spain 12,000 Year Speleothem Oxygen Isotope Data 
#---------------------------------------
# Investigators
#      Investigators: Smith, A.C.; Wynn, P.M.; Barker, P.A.; Leng, M.J.; Noble. S.R.; Tych, W.
#---------------------------------------
# Description and Notes
#        Description: Oxygen isotope (d18O) data from 2 stalagmites collected in Cueva de Asiul, Matienzo, Cantabria, Spain, 
#	 covering the past 12,000 years.  Included are the raw d18O data from stalagmites ASM and ASR (figures 2a and 2b, Smith et al. 2016), 
#	 plus combined, detrended and normalised d18O series (figure 3b, Smith et al. 2016). 
#           Provided Keywords: Holocene, climate reconstruction, northern Spain, Cueva de Asiul, NAO, Bond cycles
#---------------------------------------
# Publication
# Authors: Andrew C. Smith, Peter M. Wynn, Philip A. Barker, Melanie J. Leng, Stephen R. Noble, and Wlodek Tych
# Published_Date_or_Year: 2016-04-25
# Published_Title: North Atlantic forcing of moisture delivery to Europe throughout the Holocene 
# Journal_Name: Scientific Reports
# Volume: 6
# Edition: 24745 
# Issue: 
# Pages: 
# Report Number: 
# DOI: 10.1038/srep24745
# Online_Resource: 
# Full_Citation: 
# Abstract: Century-to-millennial scale fluctuations in precipitation and temperature are an established feature of European Holocene climates. Changes in moisture delivery are driven by complex interactions between ocean moisture sources and atmospheric circulation modes, making it difficult to resolve the drivers behind millennial scale variability in European precipitation. Here, we present two overlapping decadal resolution speleothem oxygen isotope (d18O) records from a cave on the Atlantic coastline of northern Iberia, covering the period 12.1-0 ka. Speleothem d18O reveals nine quasi-cyclical events of relatively wet-to-dry climatic conditions during the Holocene. Dynamic Harmonic Regression modelling indicates that changes in precipitation occurred with a ~1500 year frequency during the late Holocene and at a shorter length during the early Holocene. The timing of these cycles coincides with changes in North Atlantic Ocean conditions, indicating a connectivity between ocean conditions and Holocene moisture delivery. Early Holocene climate is potentially dominated by freshwater outburst events, whilst ~1500 year cycles in the late Holocene are more likely driven by changes internal to the ocean system. This is the first continental record of its type that clearly demonstrates millennial scale connectivity between the pulse of the ocean and precipitation over Europe through the entirety of the Holocene.
#---------------------------------------
# Funding_Agency
#    Funding_Agency_Name: National Environment Research Council UK
#    Grant: IP-1196-1110, IP-1323-0512, NE/I527953/1
#---------------------------------------
# Site Information
# Site_Name: Cueva de Asiul
# Location: Europe>Southern Europe>Spain
# Country: Spain
# Northernmost_Latitude: 43.32
# Southernmost_Latitude: 43.32
# Easternmost_Longitude: 3.59
# Westernmost_Longitude: 3.59
# Elevation: 285 m
#---------------------------------------
# Data_Collection
#   Collection_Name: Asiul2016composite
#   First_Year: 12148
#   Last_Year: -62
#   Time_Unit: cal. yr. BP
#   Core_Length: 
#   Notes: 
#---------------------------------------
# Chronology_Information 
# Chronology: Table S1: Detritus corrected U-Th ages for speleothems ASR and ASM. Data pertaining to the sampling locations 
# and relevant U-Th measurement data from the analysis of speleothem's ASR and ASM.
# 
# Sample Name	Depth(mm)	238Uppm	+/-2s(abs)	232Thppb	+/-2s(abs)	[230Th/232Th]	+/-2s(%)	[230Th/238U]	+/-2s(%)	[234U/238U]	+/-2s(%)	r(08-48)	Age (ka)uncorr	+/-2s(abs)	Age (ka)corr	Age(ka) BP1950 corr	+/-2s(abs)	[234U/238U](initial)	+/-2s(abs)
# ASR 
# ASR 3	5.5	0.07435	+/-0.00006	1.7266	+/-0.0040	3.4	+/-1.1	0.02002	+/-22	1.46	+/-0.30	0.0287	1.981	0.022	1.505	1.443	0.338	1.462	0.004
# ASR 9	7	0.06272	+/-0.00005	0.6024	+/-0.0008	8.6	+/-2.7	0.02454	+/-8.1	1.357	+/-0.25	0.0414	2.2	0.061	1.989	1.927	0.161	1.359	0.003
# ASR 8	21	0.1912	+/-0.00011	0.7761	+/-0.0009	35.4	+/-1.6	0.04618	+/-2.4	1.254	+/-0.14	0.0427	4.185	0.07	4.089	4.027	0.098	1.256	0.002
# ASR 7	29	0.06312	+/-0.00007	0.1658	+/-0.0004	113.9	+/-1.8	0.09766	+/-1.9	1.394	+/-0.26	0.0033	7.951	0.15	7.895	7.833	0.155	1.403	0.004
# ASR 6	41	0.08031	+/-0.00006	0.2379	+/-0.0015	120.4	+/-2.5	0.1165	+/-2.5	1.423	+/-0.18	0.0034	9.331	0.236	9.269	9.207	0.239	1.435	0.003
# ASR 5	62	0.08491	+/-0.00005	0.2361	+/-0.0007	140.1	+/-1.7	0.1273	+/-1.8	1.486	+/-0.19	0.0024	9.774	0.175	9.719	9.657	0.179	1.5	0.003
# ASR 4	80	0.07868	+/-0.00004	0.138	+/-0.0004	226	+/-1.4	0.1299	+/-1.4	1.476	+/-0.17	0.0014	10.03	0.15	9.995	9.933	0.152	1.49	0.003
# ASR 3	103	0.07885	+/-0.00008	0.1731	+/-0.0011	203.9	+/-1.8	0.1465	+/-1.8	1.515	+/-0.19	0.0011	11.073	0.208	11.031	10.969	0.21	1.532	0.003
# ASR 2	124	0.07287	+/-0.00006	0.2329	+/-0.0006	144	+/-1.8	0.1506	+/-1.9	1.564	+/-0.21	0.001	11.037	0.214	10.976	10.914	0.218	1.582	0.003
# ASR 1	152	0.1501	+/-0.00010	0.3347	+/-0.0019	225.6	+/-2.0	0.1648	+/-2.0	1.515	+/-0.15	0.0013	12.519	0.263	12.475	12.413	0.265	1.534	0.002
# ASM
# ASM 23	12.5	0.09278	+/-0.00011	0.0494	+/-0.0002	10.6	+/-6.5	0.001712	+/-9.3	1.071	+/-0.14	0.0094	0.189	0.012	0.175	0.113	0.016	1.071	0.002
# ASM 5	41.5	0.1023	+/-0.00010	0.05497	+/-0.0002	45.8	+/-1.3	0.007934	+/-1.9	1.09	+/-0.18	0.0079	0.811	0.011	0.796	0.734	0.015	1.09	0.002
# ASM 6	55.5	0.0762	+/-0.00009	0.05213	+/-0.0003	43.2	+/-1.5	0.009522	+/-2.0	1.097	+/-0.22	0.0076	0.969	0.014	0.95	0.888	0.02	1.098	0.002
# ASM 7	69.5	0.05702	+/-0.00008	0.06586	+/-0.0003	40.1	+/-1.5	0.0149	+/-2.1	1.094	+/-0.22	0.0134	1.527	0.023	1.495	1.433	0.032	1.094	0.002
# ASM 8	81.5	0.06692	+/-0.00008	0.3414	+/-0.0004	12	+/-0.99	0.01871	+/-5.3	1.096	+/-0.23	0.0811	2.016	0.021	1.877	1.815	0.101	1.096	0.003
# ASM 11	99.5	0.06374	+/-0.00008	0.07656	+/-0.0002	53.2	+/-1.2	0.02069	+/-1.6	1.093	+/-0.21	0.0149	2.116	0.025	2.083	2.021	0.034	1.094	0.002
# ASM 12	110.5	0.07907	+/-0.00007	0.08752	+/-0.0002	59.9	+/-1.2	0.0215	+/-1.6	1.091	+/-0.19	0.0135	2.2	0.027	2.17	2.108	0.035	1.092	0.002
# ASM 16	138	0.1079	+/-0.00009	0.4212	+/-0.0010	36	+/-0.60	0.04509	+/-1.7	1.175	+/-0.18	0.0601	4.361	0.028	4.262	4.2	0.076	1.177	0.002
# ASM 13	168	0.05652	+/-0.00007	0.07282	+/-0.0002	114.7	+/-1.02	0.04822	+/-1.1	1.117	+/-0.26	0.0079	4.844	0.052	4.809	4.747	0.057	1.119	0.003
# ASM 22	269.5	0.03754	+/-0.00007	0.3389	+/-0.0008	22.2	+/-0.99	0.06365	+/-2.8	1.059	+/-0.30	0.1231	7.011	0.076	6.756	6.694	0.195	1.06	0.003
# ASM 27	306	0.05361	+/-0.00015	0.03657	+/-0.0002	327.3	+/-0.53	0.07318	+/-0.59	1.063	+/-0.13	0.0067	7.791	0.046	7.772	7.707	0.048	1.065	0.001
# ASM 28	320	0.07523	+/-0.00020	0.05287	+/-0.0005	352.4	+/-0.54	0.08121	+/-0.56	1.061	+/-0.12	0.0076	8.696	0.05	8.676	8.614	0.052	1.063	0.001
# 
#---------------------------------------
# Variables
# Data variables follow that are preceded by "##" in columns one and two.
# Variables list, one per line, shortname-tab-longname components (9 components: what, material, error, units, seasonality, archive, detail, method, C or N for Character or Numeric data)

## age_calBP	age, , , calendar years before present, , , , ,N
## d18Ocarbnorm	delta18O normalized, calcium carbonate, y = 0.1 per mil; x = stalage, per mil VPDB, ,speleothem, reference period: 1981-1986 A.D.,analytical technique: isotope ratio mass spectrometry,N 
## d18Odetrend	delta18O detrended cycle, calcium carbonate, , per mil VPDB, ,speleothem, , ,N 
#------------------------
# Data
# Data lines follow (have no #)
# Data line format - tab-delimited text, variable short name as header
# Missing Value: NaN
#
age_calBP	d18Ocarbnorm	d18Odetrend
-62	-0.0452	-0.0053
-47	0.1168	0.0052
-32	0.2571	0.0179
-17	0.1858	0.0326
-2	-0.0490	0.0492
13	-0.0234	0.0676
28	-0.0246	0.0875
43	-0.0452	0.1083
58	0.0179	0.1296
73	0.1138	0.1508
88	0.2658	0.1712
103	0.2386	0.1902
118	0.1640	0.2072
133	0.0602	0.2218
148	0.0497	0.2336
163	0.2909	0.2423
178	0.2926	0.2474
193	0.3346	0.2490
208	0.3491	0.2470
223	0.3246	0.2416
238	0.3933	0.2330
253	0.2702	0.2215
268	0.2124	0.2079
283	0.1897	0.1925
298	0.2032	0.1761
313	0.2848	0.1593
328	-0.0019	0.1425
343	-0.2578	0.1266
358	-0.2498	0.1121
373	-0.0730	0.0995
388	0.0248	0.0887
403	-0.0005	0.0800
418	0.0360	0.0733
433	0.2834	0.0683
448	0.2402	0.0648
463	0.1100	0.0623
478	0.1823	0.0605
493	0.3167	0.0587
508	0.2632	0.0564
523	0.1977	0.0530
538	0.2657	0.0480
553	0.2192	0.0410
568	0.1058	0.0315
583	0.0726	0.0193
598	0.1414	0.0043
613	-0.1377	-0.0137
628	-0.2480	-0.0342
643	-0.2959	-0.0571
658	-0.2766	-0.0820
673	-0.1926	-0.1083
688	-0.0573	-0.1355
703	0.0769	-0.1630
718	0.0741	-0.1902
733	-0.2566	-0.2163
748	-0.3857	-0.2403
763	-0.3778	-0.2613
778	-0.2981	-0.2787
793	-0.4172	-0.2919
808	-0.3732	-0.3004
823	-0.3659	-0.3039
838	-0.3417	-0.3023
853	-0.1996	-0.2955
868	-0.1297	-0.2839
883	-0.2137	-0.2679
898	-0.0891	-0.2478
913	-0.2087	-0.2245
928	-0.3150	-0.1985
943	-0.2833	-0.1708
958	-0.3854	-0.1421
973	-0.0949	-0.1134
988	0.1202	-0.0857
1003	0.0143	-0.0600
1018	-0.0005	-0.0370
1033	0.0917	-0.0174
1048	0.1594	-0.0016
1063	0.1211	0.0099
1078	0.0055	0.0170
1093	-0.1030	0.0200
1108	-0.1273	0.0189
1123	-0.0621	0.0144
1138	-0.0249	0.0068
1153	-0.0854	-0.0031
1168	-0.0653	-0.0147
1183	-0.0791	-0.0269
1198	-0.0832	-0.0391
1213	-0.0833	-0.0502
1228	-0.0918	-0.0595
1243	-0.1364	-0.0663
1258	-0.1485	-0.0697
1273	-0.0428	-0.0695
1288	0.0809	-0.0651
1303	0.1117	-0.0566
1318	0.1027	-0.0439
1333	0.1320	-0.0272
1348	0.1561	-0.0068
1363	0.0004	0.0168
1378	-0.0270	0.0431
1393	-0.1029	0.0714
1408	-0.1465	0.1009
1423	-0.1121	0.1309
1438	0.0136	0.1603
1453	0.1664	0.1882
1468	0.4333	0.2138
1483	0.3864	0.2360
1498	0.3969	0.2543
1513	0.5169	0.2681
1528	0.5777	0.2772
1543	0.5227	0.2812
1558	0.3313	0.2803
1573	0.2058	0.2748
1588	0.1807	0.2651
1603	0.2670	0.2517
1618	0.2081	0.2352
1633	0.1650	0.2163
1648	0.2859	0.1958
1663	0.2324	0.1743
1678	0.3058	0.1526
1693	0.2165	0.1315
1708	0.1964	0.1115
1723	0.3371	0.0932
1738	0.1104	0.0771
1753	-0.1294	0.0634
1768	-0.0263	0.0525
1783	0.0524	0.0445
1798	-0.1079	0.0390
1813	-0.2688	0.0359
1828	-0.2637	0.0349
1843	-0.1592	0.0355
1858	-0.0365	0.0371
1873	-0.0701	0.0389
1888	-0.2010	0.0404
1903	0.0527	0.0411
1918	0.0955	0.0402
1933	0.1614	0.0372
1948	0.2490	0.0317
1963	0.1124	0.0234
1978	0.1362	0.0122
1993	-0.0354	-0.0017
2008	-0.0766	-0.0182
2023	0.0192	-0.0369
2038	0.1655	-0.0571
2053	0.0684	-0.0791
2068	0.0263	-0.1018
2083	0.1694	-0.1247
2098	-0.0136	-0.1472
2113	-0.4853	-0.1684
2128	-0.6182	-0.1876
2143	-0.4872	-0.2041
2158	-0.4213	-0.2175
2173	-0.4569	-0.2276
2188	-0.4304	-0.2343
2203	-0.4545	-0.2373
2218	-0.4139	-0.2369
2233	-0.1461	-0.2333
2248	0.0135	-0.2269
2263	0.0039	-0.2182
2278	-0.0357	-0.2076
2293	-0.0770	-0.1956
2308	-0.1072	-0.1826
2323	-0.1081	-0.1691
2338	-0.1215	-0.1555
2353	-0.0720	-0.1421
2368	-0.0415	-0.1294
2383	-0.0403	-0.1175
2398	-0.0242	-0.1066
2413	-0.0216	-0.0967
2428	-0.0187	-0.0878
2443	0.0004	-0.0799
2458	-0.0947	-0.0727
2473	-0.1650	-0.0660
2488	-0.0702	-0.0595
2503	-0.1751	-0.0529
2518	-0.1742	-0.0459
2533	-0.0434	-0.0383
2548	0.1352	-0.0300
2563	-0.0005	-0.0209
2578	0.0046	-0.0109
2593	0.0344	0.0000
2608	-0.0989	0.0118
2623	-0.1534	0.0244
2638	-0.0116	0.0377
2653	0.1102	0.0512
2668	0.1650	0.0648
2683	0.2036	0.0778
2698	0.2615	0.0901
2713	0.2445	0.1013
2728	0.2289	0.1110
2743	0.3025	0.1189
2758	0.3529	0.1250
2773	0.2081	0.1290
2788	0.1550	0.1309
2803	0.0126	0.1309
2818	-0.0011	0.1291
2833	0.0265	0.1257
2848	-0.0203	0.1210
2863	-0.0064	0.1153
2878	-0.0251	0.1088
2893	-0.0369	0.1020
2908	0.0144	0.0952
2923	0.0701	0.0887
2938	0.0447	0.0828
2953	-0.0016	0.0779
2968	0.0962	0.0742
2983	0.1352	0.0717
2998	0.0677	0.0707
3013	0.0413	0.0711
3028	0.0868	0.0729
3043	0.0971	0.0760
3058	0.0780	0.0802
3073	0.0516	0.0853
3088	0.0816	0.0909
3103	0.0696	0.0967
3118	0.0860	0.1024
3133	0.2054	0.1076
3148	0.1896	0.1118
3163	0.1427	0.1148
3178	0.1768	0.1162
3193	0.1808	0.1159
3208	0.1108	0.1136
3223	0.1038	0.1093
3238	0.1070	0.1030
3253	0.0856	0.0947
3268	0.0407	0.0846
3283	0.0269	0.0729
3298	0.0588	0.0598
3313	0.1204	0.0456
3328	0.1050	0.0307
3343	-0.0168	0.0153
3358	-0.0879	-0.0001
3373	-0.0730	-0.0151
3388	-0.0831	-0.0294
3403	-0.0913	-0.0427
3418	-0.0655	-0.0548
3433	-0.0492	-0.0655
3448	-0.0275	-0.0747
3463	-0.0099	-0.0824
3478	-0.0181	-0.0887
3493	-0.0540	-0.0935
3508	-0.0925	-0.0971
3523	-0.1887	-0.0995
3538	-0.2452	-0.1010
3553	-0.1481	-0.1016
3568	-0.2205	-0.1019
3583	-0.1717	-0.1020
3598	-0.1241	-0.1021
3613	-0.1822	-0.1026
3628	-0.2307	-0.1036
3643	-0.0987	-0.1052
3658	-0.0285	-0.1075
3673	0.0056	-0.1108
3688	0.0653	-0.1148
3703	0.1287	-0.1196
3718	-0.3133	-0.1248
3733	NaN	-0.1303
3748	-0.2859	-0.1357
3763	-0.1852	-0.1405
3778	NaN	-0.1445
3793	NaN	-0.1474
3808	0.0184	-0.1488
3823	-0.1105	-0.1485
3838	-0.2633	-0.1461
3853	-0.2046	-0.1414
3868	-0.0993	-0.1343
3883	0.0409	-0.1246
3898	-0.0201	-0.1127
3913	0.0259	-0.0984
3928	0.2822	-0.0820
3943	0.2711	-0.0640
3958	0.2150	-0.0445
3973	-0.0901	-0.0240
3988	-0.6419	-0.0027
4003	-0.8411	0.0193
4018	-0.3876	0.0416
4033	-0.1421	0.0634
4048	-0.1466	0.0840
4063	-0.0025	0.1027
4078	0.3455	0.1191
4093	0.4163	0.1325
4108	0.3001	0.1425
4123	0.2173	0.1489
4138	0.4570	0.1516
4153	0.4671	0.1506
4168	0.2187	0.1458
4183	0.1457	0.1378
4198	0.2214	0.1269
4213	0.1213	0.1135
4228	0.0307	0.0980
4243	0.0520	0.0813
4258	-0.0050	0.0637
4273	-0.0177	0.0460
4288	-0.1349	0.0288
4303	-0.3539	0.0125
4318	-0.1067	-0.0020
4333	0.0938	-0.0147
4348	0.2288	-0.0252
4363	0.2574	-0.0333
4378	0.1639	-0.0390
4393	0.0808	-0.0421
4408	0.0917	-0.0426
4423	0.0473	-0.0404
4438	0.0650	-0.0358
4453	-0.0108	-0.0290
4468	-0.1804	-0.0203
4483	-0.2932	-0.0099
4498	-0.2666	0.0019
4513	-0.0520	0.0147
4528	-0.1240	0.0278
4543	-0.2771	0.0408
4558	-0.2236	0.0535
4573	-0.0358	0.0653
4588	0.1523	0.0759
4603	0.3123	0.0848
4618	0.3830	0.0917
4633	0.4753	0.0964
4648	0.4811	0.0988
4663	0.3252	0.0988
4678	0.1226	0.0968
4693	0.2566	0.0931
4708	0.2645	0.0877
4723	0.1373	0.0809
4738	0.1486	0.0732
4753	0.1402	0.0647
4768	0.1437	0.0559
4783	0.1150	0.0470
4798	-0.0214	0.0382
4813	-0.0534	0.0300
4828	-0.0630	0.0223
4843	-0.0770	0.0154
4858	-0.0300	0.0092
4873	0.1016	0.0038
4888	-0.0100	-0.0010
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4918	0.1450	-0.0090
4933	0.1259	-0.0126
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5008	-0.1555	-0.0321
5023	-0.1591	-0.0367
5038	-0.1940	-0.0416
5053	-0.2615	-0.0467
5068	-0.0112	-0.0520
5083	0.1617	-0.0575
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5263	-0.2955	-0.0769
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5383	0.0392	0.0009
5398	0.0760	0.0111
5413	0.1647	0.0204
5428	0.2670	0.0286
5443	0.2757	0.0355
5458	0.1946	0.0408
5473	0.0028	0.0447
5488	-0.1963	0.0471
5503	-0.1176	0.0482
5518	-0.0638	0.0481
5533	-0.2676	0.0467
5548	-0.0698	0.0443
5563	-0.0183	0.0409
5578	-0.0867	0.0366
5593	0.1454	0.0315
5608	0.2467	0.0256
5623	0.0016	0.0190
5638	-0.0902	0.0121
5653	0.1117	0.0049
5668	-0.0320	-0.0024
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5743	0.3428	-0.0357
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5788	-0.0334	-0.0511
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5818	0.1004	-0.0575
5833	-0.0543	-0.0595
5848	-0.2483	-0.0605
5863	-0.2787	-0.0606
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5923	-0.0165	-0.0505
5938	0.1555	-0.0458
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5968	-0.1870	-0.0349
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5998	-0.1766	-0.0219
6013	-0.1122	-0.0149
6028	0.2924	-0.0077
6043	0.1236	-0.0007
6058	-0.0354	0.0060
6073	-0.0844	0.0126
6088	-0.2082	0.0188
6103	-0.1997	0.0246
6118	-0.0498	0.0301
6133	-0.0418	0.0349
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6163	-0.0082	0.0427
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6283	0.3884	0.0475
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6313	0.1710	0.0451
6328	-0.0154	0.0441
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6388	-0.0039	0.0455
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6463	-0.0342	0.0587
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6748	-0.0029	-0.0044
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7798	NaN	NaN
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