# NOAA Paleoclimatology Program - Speleothem Site Data # cave-springvalley-svc-1.txt # Speleothem data only # File Created: 23-March-2011 # #********************************************************************************* # Please cite the contributor and the original publications when using these data #********************************************************************************* # # Missing Values indicated by '-999' # # PI: R.F. Denniston # Core/Site: SVC-1/Spring valley Cave # Latitude: 43° 44' 45"N # Longitude: 92° 24' 49"W # Elevation: 397 m # # Publications: # Denniston, R.F., L.A. González, R.G. Baker, Y. Asmerom, M.K. Reagan, # R.L. Edwards, and C. Alexander. 1999. # Speleothem evidence for Holocene fluctuations of the # prairie-forest ecotone, north-central USA. # Holocene, 9, 671-676, # DOI: 10.1191/095968399674716399 # #------------------ # # Description & Notes: # Stable isotope data (13C and 18O) of two stalagmites from # Spring Valley Caverns Minnesota (SVC-IV - North Crawl) # Stalagmites dated by U-Th Series, and isotope data # collected on a Finnigan MAT 252 using a Kiel II device. # #------------------ # # 230Th dating # Sample! mm from* 238U 232Th d234U§ 230Th/238U 230Th/232Th Age† # bottom (ng/g) (pg/g measured activity atomic # SV-1 23 1260 2400 660 (3) 0.123 (1) 1.07e-3 (1) 8340 (90) # SV-1 76 1340 1340 650 (3) 0.116 (90) 1.91e-3 (2) 7880 (60) # SV-1 200 1590 780 690 (4) 6.90e-2 (3) 2.31e-3 (2) 4510 (30) # SV-1 277 2410 690 630 (2) 6.34e-2 (4) 3.65e-3 (60) 4300 (30) # SV-1 375 1570 480 670 (10) 5.14e-2 (3) 2.75e-3 (3) 3400 (30) # SV-1 535 1920 4080 660 (3) 2.63e-2 (9) 2.04e-4 (8) 1700 (60) # SV-1 602 1730 2190 710 (5) 1.06e-2 (1) 1.37e-4 (2) 650 (10) # # ! Analyses of Cold Water Cave stalagmite 1S are tabuluated in Dorale et al. (1992). # * The total length of SV-1 = 635 mm; SV-2 = 560 mm; MC-28 = 317 mm; CC-A = 311 mm. # §d234Umeasured = [(234U/238U)measured/(234U/238U)eq –1] × 103, where (234U/238U)eq is # the secular equilibrium atomic ratio: lamda238/lamda234 = 5.472 × 10- 5. Values in # parentheses are 2sigma uncertainties. # # † Ages are relative to the time of measurement, 1994–1996. Ages are calculated using a # modification of the standard age equations (Broecker and Thurber,1965) # modified to correct for initial 230Th assuming an initial 230Th/232Th ratio of # 4.4 × 10- 6(± 2.2 × 10- 6). Half lives are those used in Edwards et al. # (1987). Although analytically precise, uncertainty associated with drilling large # (~1 g) samples increases the effective error of these dates. # #---------------- # # Variables: # age_calBP Age (calendar years BP) # d13CcarbPDB delta13C calcium carbonate (per mil PDB) # d18OcarbSMOW delta18O calcium carbonate (per mil SMOW) # # CORE: SVC-1 age_calBP d13CcarbPDB d18OcarbSMOW 0 -6.16 24.58 39 -5.51 24.99 59 -6.45 24.57 110 -8.93 24.07 167 -8.21 24.19 236 -8.2 24.57 315 -9.17 24.05 443 -7.49 24.15 559 -7.45 24.37 650 -7.06 24.43 721 -7.45 24.14 792 -7.45 24.02 863 -7.2 24.4 952 -6.92 24.38 1041 -7.34 24.19 1183 -7.05 24.23 1275 -7 24.2 1396 -7.89 24.13 1521 -7.92 23.84 1645 -8.08 23.98 1731 -8.34 24.37 1790 -8.06 24.29 1851 -7.85 24.29 1912 -9.02 24.07 1972 -8.87 24.09 2033 -7.75 24.49 2084 -8.43 24.44 2134 -8.38 24.39 2192 -7.4 24.64 2278 -7.31 25.02 2357 -7.05 24.99 2421 -6.86 25.14 2491 -6.7 25.29 2582 -6.73 25.27 2661 -6.37 25.47 2742 -6.53 25.32 2823 -6.41 25.69 2896 -5.49 25.65 2924 -6.02 25.62 2960 -5.61 25.95 2975 -6.05 25.88 3003 -5.78 25.66 3030 -6.24 26.73 3047 -5.9 25.76 3076 -5.97 25.73 3096 -5.82 25.83 3119 -5.39 25.9 3147 -5.67 25.81 3167 -5.93 25.66 3187 -6.05 25.74 3213 -6.2 25.33 3243 -5.17 25.75 3268 -6 25.59 3294 -5.69 25.89 3306 -4.49 26.15 3327 -5.01 25.7 3349 -6.38 25.7 3370 -6 26.19 3390 -6.32 25.72 3411 -5.93 25.94 3428 -6.3 25.97 3446 -5.83 26.36 3466 -6.52 26.06 3484 -6.44 25.9 3506 -6.19 26.11 3527 -6.63 25.66 3545 -6.57 25.83 3570 -6.21 25.79 3591 -5.58 26.31 3609 -6.66 25.81 3634 -6.61 25.75 3655 -6.66 26.23 3676 -6.65 25.95 3698 -6.59 25.9 3721 -6.31 25.73 3746 -6.79 25.79 3767 -6.67 25.99 3786 -7.18 25.64 3804 -7.14 25.8 3827 -6.11 25.82 3845 -6.2 26.06 3867 -6.17 25.88 3887 -5.33 25.98 3910 -6.54 25.82 3933 -5.81 26.25 3956 -6.12 25.8 3979 -6.6 26.18 3995 -7.01 26.1 4011 -6.52 25.81 4034 -6 26.28 4052 -6.85 25.99 4075 -6.7 26.13 4093 -6.11 26.25 4112 -6.08 25.59 4130 -5.81 26.24 4153 -6.03 25.7 4185 -6.09 26.22 4199 -5.74 26.13 4199 -5.74 26.13 4227 -5.28 25.81 4245 -5.31 26.36 4263 -5.81 26.38 4286 -5.4 26.09 4303 -6.35 25.79 4308 -6.07 26.06 4315 -5.36 25.97 4322 -5.5 25.99 4327 -5.58 26.24 4334 -5.49 25.89 4341 -5.72 26.41 4347 -5.51 26.21 4355 -5.24 26.03 4360 -5.02 26.2 4365 -5.52 26.17 4374 -5.87 26.11 4379 -5.28 26.28 4385 -6.24 26.21 4393 -5.95 25.74 4400 -5.5 26.38 4406 -5.78 26.51 4413 -6.24 25.98 4421 -4.94 26.07 4428 -5.5 26.28 4435 -5 25.86 4442 -4.75 26.23 4447 -5.71 26.07 4455 -5.61 25.92 4461 -5.98 26.07 4466 -5.42 25.99 4475 -5.44 25.73 4484 -5.57 25.83 4490 -6.08 26.49 4499 -5.51 26.2 4507 -4.3 26.45 4537 -3.57 26.5 4564 -5.6 26.23 4632 -5.54 25.78 4700 -5.98 25.58 4782 -6.13 25.85 4849 -5.28 25.6 4917 -5.43 26.08 4996 -6.38 25.98 5053 -5.5 25.71 5121 -4.79 26.13 5183 -5.17 26.11 5257 -5.19 25.98 5298 -4.55 26.42 5379 -4.6 25.98 5422 -4.92 25.63 5474 -5.11 25.58 5542 -5.69 25.71 5591 -5.64 25.61 5637 -4.55 25.39 5664 -5.07 25.43 5718 -6.2 24.99 5767 -4.35 26.51 5813 -4.18 26.4 5868 -4.22 26.39 5909 -5.22 26.12 5949 -5.29 26.15 5990 -4.35 26.39 6031 -4.89 26.55 6099 -4.7 26.57 6166 -5.1 26.25 6226 -5.13 25.92 6302 -5.8 26.09 6370 -5.64 25.89 6438 -4.82 26.13 6492 -5.07 25.67 6547 -6.15 25.64 6615 -5.61 25.53 6669 -6.21 25.69 6737 -5.94 25.5 6791 -5.61 26.1 6851 -6.26 25.66 6927 -5.82 25.73 6995 -5.36 25.44 7063 -5.93 25.67 7117 -5.86 25.45 7185 -5.77 25.64 7231 -6.69 25.74 7321 -6.07 25.36 7375 -6.08 25.43 7443 -5.75 25.66 7511 -5.42 25.83 7579 -4.47 26.39 7633 -5.18 25.7 7687 -4.81 25.63 7742 -6.66 24.76 7796 -6.66 25.4 7864 -6.57 24.66 7892 -6.74 24.95 7907 -7.4 24.62 7927 -6.97 24.28 7948 -7.56 24.44 7965 -7.12 24.58 7987 -8.13 24.16 8004 -9.15 23.73 8021 -8.85 24.49 8043 -9.46 23.85 8060 -9.55 23.9 8077 -9.35 24.15 8099 -8.29 24.42 8116 -8.76 24.29 8138 -8.85 24.42 8155 -8.6 24.43 8168 -8.41 24.43 8185 -9.52 24.21 8206 -9 24.39 8232 -8.84 24.29 8254 -8.66 24.64 8275 -9.18 24.1 8293 -9.81 23.96 8310 -8.48 24.61 8327 -8.85 24.78 8349 -9.56 24.13 8370 -8.89 24.57 8392 -10.12 24.55 8413 -10.26 24.39 8429 -10.2 24.53 8439 -10.17 24.57 8456 -8.58 24.9 8474 -9.69 24.53 8491 -9.67 24.2 8504 -9.98 24.1 8517 -9.85 24.57